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Far-red luminescent ruthenium pyridylimine complexes; building blocks for multinuclear arrays
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UNSPECIFIED (2006) Far-red luminescent ruthenium pyridylimine complexes; building blocks for multinuclear arrays. DALTON TRANSACTIONS (24). pp. 3025-3034. doi:10.1039/b518027a ISSN 1477-9226.
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Official URL: http://dx.doi.org/10.1039/b518027a
Abstract
Ruthenium(II) pyridylimine complexes are explored for their potential as units that might be incorporated into electronic or photonic arrays. The complexes [Ru(bipy)(2)(L)][PF6](2) (1) and [Ru(tpy)(L)Cl][BF4] (2) with L = phenylpyridin-2-ylmethylene-amine are synthesized and fully characterised using X-ray diffraction analysis and (2D) NMR spectroscopy. 1 displays emission in the far-red area of the spectrum at room temperature. The emission is significantly shifted to longer wavelength with respect to [Ru(bpy)(3)](2+) indicating that the lowest MLCT state is localised on the pyridylimine ligand. 2 is non-emissive at room temperature and at 77 K.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Journal or Publication Title: | DALTON TRANSACTIONS | ||||
| Publisher: | ROYAL SOC CHEMISTRY | ||||
| ISSN: | 1477-9226 | ||||
| Official Date: | 2006 | ||||
| Dates: |
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| Number: | 24 | ||||
| Number of Pages: | 10 | ||||
| Page Range: | pp. 3025-3034 | ||||
| DOI: | 10.1039/b518027a | ||||
| Publication Status: | Published |
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