Rusanova, Daniela, Forsling, Willis, Antzutkin, Oleg N., Pike, Kevin J. and Dupree, Ray. (2006) Solid-state P-31 CP/MAS and static Cu-65 NMR characterization of polycrystalline copper(I) dialkyldithiophosphate clusters. Journal of Magnetic Resonance, Vol.179 (No.1). pp. 140-145. ISSN 1090-7807

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Abstract

Polycrystalline tetra-nuclear Cu-4[S2P(O-i-C3H7)(2)](4), hexa-nuclear Cu-6[S2P(OC2H5)(2)](6), and octa-nuclear Cu-8[S2P(O-i-C4H9)(2)](6)(S) complexes were synthesized and analyzed by means of solid-state (31)p CP/MAS and (CU)-C-65 static NMR spectroscopy. The symmetries of the electronic environments around each P-site were estimated from the P-31 chemical shift anisotropy (CSA) parameters, Delta(aniso) and eta. The (CU)-C-65 chernical shift and quadrupolar splitting parameters obtained from the experimental Cu-65 NMR spectra of the polycrystalline Cu-1-complexes are presented. A solid-state NMR approach for the elucidation of the stereochemistry of poly-nuclear Cu(I) dithiophosphate complexes, when the structural analysis of the systems by single-crystal X-ray diffraction is not readily available, is proposed. (c) 2005 Elsevier Inc. All rights reserved.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry Q Science > QC Physics
Divisions:	Faculty of Science > Physics
Journal or Publication Title:	Journal of Magnetic Resonance
Publisher:	Academic Press
ISSN:	1090-7807
Official Date:	March 2006
Volume:	Vol.179
Number:	No.1
Number of Pages:	6
Page Range:	pp. 140-145
Identification Number:	10.1016/j.jmr.2005.10.013
Status:	Peer Reviewed
Publication Status:	Published
Funder:	Swedish Council for Planning and Coordination of Research (FRN), Foundation to the memory of J.C. and Seth M. Kempe
URI:	http://wrap.warwick.ac.uk/id/eprint/33650

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