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Solid-state P-31 CP/MAS and static Cu-65 NMR characterization of polycrystalline copper(I) dialkyldithiophosphate clusters
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Rusanova, Daniela, Forsling, Willis, Antzutkin, Oleg N., Pike, Kevin J. and Dupree, Ray (2006) Solid-state P-31 CP/MAS and static Cu-65 NMR characterization of polycrystalline copper(I) dialkyldithiophosphate clusters. Journal of Magnetic Resonance, Vol.179 (No.1). pp. 140-145. doi:10.1016/j.jmr.2005.10.013
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Official URL: http://dx.doi.org/10.1016/j.jmr.2005.10.013
Abstract
Polycrystalline tetra-nuclear Cu-4[S2P(O-i-C3H7)(2)](4), hexa-nuclear Cu-6[S2P(OC2H5)(2)](6), and octa-nuclear Cu-8[S2P(O-i-C4H9)(2)](6)(S) complexes were synthesized and analyzed by means of solid-state (31)p CP/MAS and (CU)-C-65 static NMR spectroscopy. The symmetries of the electronic environments around each P-site were estimated from the P-31 chemical shift anisotropy (CSA) parameters, Delta(aniso) and eta. The (CU)-C-65 chernical shift and quadrupolar splitting parameters obtained from the experimental Cu-65 NMR spectra of the polycrystalline Cu-1-complexes are presented. A solid-state NMR approach for the elucidation of the stereochemistry of poly-nuclear Cu(I) dithiophosphate complexes, when the structural analysis of the systems by single-crystal X-ray diffraction is not readily available, is proposed. (c) 2005 Elsevier Inc. All rights reserved.
| Item Type: | Journal Article | ||||
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| Subjects: | Q Science > QD Chemistry Q Science > QC Physics |
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| Divisions: | Faculty of Science > Physics | ||||
| Journal or Publication Title: | Journal of Magnetic Resonance | ||||
| Publisher: | Academic Press | ||||
| ISSN: | 1090-7807 | ||||
| Official Date: | March 2006 | ||||
| Dates: |
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| Volume: | Vol.179 | ||||
| Number: | No.1 | ||||
| Number of Pages: | 6 | ||||
| Page Range: | pp. 140-145 | ||||
| DOI: | 10.1016/j.jmr.2005.10.013 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Funder: | Swedish Council for Planning and Coordination of Research (FRN), Foundation to the memory of J.C. and Seth M. Kempe |
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