The Library

Solid-state P-31 CP/MAS and static Cu-65 NMR characterization of polycrystalline copper(I) dialkyldithiophosphate clusters

Tools

Rusanova, Daniela, Forsling, Willis, Antzutkin, Oleg N., Pike, Kevin J. and Dupree, Ray. (2006) Solid-state P-31 CP/MAS and static Cu-65 NMR characterization of polycrystalline copper(I) dialkyldithiophosphate clusters. Journal of Magnetic Resonance, Vol.179 (No.1). pp. 140-145. ISSN 1090-7807

Full text not available from this repository.

Official URL: http://dx.doi.org/10.1016/j.jmr.2005.10.013

Abstract

Polycrystalline tetra-nuclear Cu-4[S2P(O-i-C3H7)(2)](4), hexa-nuclear Cu-6[S2P(OC2H5)(2)](6), and octa-nuclear Cu-8[S2P(O-i-C4H9)(2)](6)(S) complexes were synthesized and analyzed by means of solid-state (31)p CP/MAS and (CU)-C-65 static NMR spectroscopy. The symmetries of the electronic environments around each P-site were estimated from the P-31 chemical shift anisotropy (CSA) parameters, Delta(aniso) and eta. The (CU)-C-65 chernical shift and quadrupolar splitting parameters obtained from the experimental Cu-65 NMR spectra of the polycrystalline Cu-1-complexes are presented. A solid-state NMR approach for the elucidation of the stereochemistry of poly-nuclear Cu(I) dithiophosphate complexes, when the structural analysis of the systems by single-crystal X-ray diffraction is not readily available, is proposed. (c) 2005 Elsevier Inc. All rights reserved.

Item Type:

Journal Article

Subjects:

Q Science > QD Chemistry
Q Science > QC Physics

Divisions:

Faculty of Science > Physics

Journal or Publication Title:

Journal of Magnetic Resonance

Publisher:

Academic Press

ISSN:

1090-7807