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Synthesis and characterisation of alkali metal and thallium polyfluoroantimonates, ASb(n)F(5n+1) (n=2, 3)
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UNSPECIFIED (2006) Synthesis and characterisation of alkali metal and thallium polyfluoroantimonates, ASb(n)F(5n+1) (n=2, 3). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (5). pp. 1084-1092. doi:10.1002/ejic.200500856 ISSN 1434-1948.
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Official URL: http://dx.doi.org/10.1002/ejic.200500856
Abstract
the other hand, is monoclinic at 250 K [P2(1)/n, with a 774.10(14), b = 1425.41(17)m, c = 951.30(15) pm, beta 113.226(6)degrees, V = 0.9646(3) nm(3) and Z = 4]. RbSb2F11 and TISb2F11 belong to yet a third structural type. Crystals of CsSb3F16 are orthorhombic at 200 K [Pca2(1), with a = 2207(3), b = 772.6(11), c = 1605(3) pm, V = 2.737(8) nm(3) and Z = 8]. The vibrational spectra of Sb2F11- salts are consistent with the above crystallographic assignments, showing that Sb2F11- anions deviate strongly from D-4h symmetry in having no symmetry at all (point group C-1). The vibrational spectra of CsSb3F16 confirm the presence of Sb3F16- anions, which adopt a cis-fluorine-bridged geometry consistent with the crystal structure. (c) Wiley-VCH Verlag GmbH & Co.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | ||||
Publisher: | WILEY-V C H VERLAG GMBH | ||||
ISSN: | 1434-1948 | ||||
Official Date: | 6 March 2006 | ||||
Dates: |
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Number: | 5 | ||||
Number of Pages: | 9 | ||||
Page Range: | pp. 1084-1092 | ||||
DOI: | 10.1002/ejic.200500856 | ||||
Publication Status: | Published |
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