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Cyclopalladated acetate dimers: crystal structures and VT-NMR
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UNSPECIFIED (2006) Cyclopalladated acetate dimers: crystal structures and VT-NMR. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 691 (6). pp. 1251-1256. doi:10.1016/j.jorganchem.2005.11.066 ISSN 0022-328X.
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Official URL: http://dx.doi.org/10.1016/j.jorganchem.2005.11.066
Abstract
The X-ray structure of two cyclopalladated acetate bridged dimers has been solved, and they are shown to exhibit all open-book type core, analogous to those that have been previously reported. Variable temperature NMR studies oil these molecules demonstrates that this core persists in chloroform solution, resulting in restrictions to the movement of ancillary parts of the molecule. The barrier to rotation of a pendant phenyl ring against this core hits been measured: Delta H-double dagger = 56 kJ mol(-1), and Delta S-double dagger = 0. (c) 2005 Elsevier B.V. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF ORGANOMETALLIC CHEMISTRY | ||||
Publisher: | ELSEVIER SCIENCE SA | ||||
ISSN: | 0022-328X | ||||
Official Date: | 1 March 2006 | ||||
Dates: |
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Volume: | 691 | ||||
Number: | 6 | ||||
Number of Pages: | 6 | ||||
Page Range: | pp. 1251-1256 | ||||
DOI: | 10.1016/j.jorganchem.2005.11.066 | ||||
Publication Status: | Published |
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