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654. Photochemical transformations. Part XIX. Some photosensitive protecting groups
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Barton, D. H. R., Chow, Y. L., Cox, A. and Kirby, G. W.. (1965) 654. Photochemical transformations. Part XIX. Some photosensitive protecting groups. Journal of the Chemical Society (Resumed) . pp. 3571-3578. ISSN 0368-1769
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Official URL: http://dx.doi.org/10.1039/JR9650003571
Abstract
The photolysis of 2,4-dinitrobenzenesulphenyl esters affords carboxylic acids in high yield. The initial step in this photolysis has been defined. The photolysis of phenolic esters has been further investigated. The esters of fluorene-9-carboxylic acid and xanthen-9-carboxylic acid afford reasonable yields of phenols with concomitant fragmentation of the acid residue. The potential advantages of protecting groups which can be removed photochemically under neutral conditions have been emphasised. A preliminary report of some aspects of our work has appeared.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Chemistry |
| Journal or Publication Title: | Journal of the Chemical Society (Resumed) |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 0368-1769 |
| Date: | 1965 |
| Page Range: | pp. 3571-3578 |
| Identification Number: | 10.1039/JR9650003571 |
| Status: | Peer Reviewed |
| Description: | Data sourced from: Butterworth, J. (1966). Report of the Vice Chancellor 1965-66. Coventry : University of Warwick. |
| URI: | http://wrap.warwick.ac.uk/id/eprint/34924 |
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