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654. Photochemical transformations. Part XIX. Some photosensitive protecting groups

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Barton, D. H. R., Chow, Y. L., Cox, A. and Kirby, G. W. (1965) 654. Photochemical transformations. Part XIX. Some photosensitive protecting groups. Journal of the Chemical Society (Resumed) . pp. 3571-3578. doi:10.1039/JR9650003571 ISSN 0368-1769.

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Official URL: http://dx.doi.org/10.1039/JR9650003571

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Abstract

The photolysis of 2,4-dinitrobenzenesulphenyl esters affords carboxylic acids in high yield. The initial step in this photolysis has been defined. The photolysis of phenolic esters has been further investigated. The esters of fluorene-9-carboxylic acid and xanthen-9-carboxylic acid afford reasonable yields of phenols with concomitant fragmentation of the acid residue. The potential advantages of protecting groups which can be removed photochemically under neutral conditions have been emphasised. A preliminary report of some aspects of our work has appeared.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Journal or Publication Title: Journal of the Chemical Society (Resumed)
Publisher: Royal Society of Chemistry
ISSN: 0368-1769
Official Date: 1965
Dates:
DateEvent
1965Published
Page Range: pp. 3571-3578
DOI: 10.1039/JR9650003571
Status: Peer Reviewed
Description:

Data sourced from: Butterworth, J. (1966). Report of the Vice Chancellor 1965-66. Coventry : University of Warwick.

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