Cotton, J. D. and Waddington, T. C. (Thomas Cudworth). (1966) Liquid hydrogen sulphide as an ionising solvent. Part I. Base analogues and their neutralisation with hydrogen halides. Journal of the Chemical Society A: Inorganic, Physical, Theoretical . pp. 785-789. ISSN 0022-4944

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Abstract

Tetra-alkylammonium hydrogen sulphides, R4NSH, have been prepared. The salts co-ordinate hydrogen sulphide loosely at low temperatures; the hydrogen-bond energy is about 5 kcal. mole–1. Solutions of the salts in liquid hydrogen sulphide are strongly conducting, compared with solutions of amines and phosphines. A hydrogen dichloride salt was formed in the neutralisation of tetra-n-propylammonium hydrogen sulphide in liquid hydrogen sulphide. Similar reaction of hydrogen halides with tetra-alkylammonium halides in liquid hydrogen sulphide gave salts containing the anions, HCl2–, HBr2–, Hl2–, HBrCl–, and HCll–.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Journal or Publication Title:	Journal of the Chemical Society A: Inorganic, Physical, Theoretical
Publisher:	Royal Chemical Society
ISSN:	0022-4944
Date:	1966
Page Range:	pp. 785-789
Identification Number:	10.1039/J19660000785
Status:	Peer Reviewed
Description:	Data sourced from: Butterworth, J. (1966). Report of the Vice Chancellor 1965-66. Coventry : University of Warwick.
URI:	http://wrap.warwick.ac.uk/id/eprint/34929

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