Liquid hydrogen sulphide as an ionising solvent. Part I. Base analogues and their neutralisation with hydrogen halides
Cotton, J. D. and Waddington, T. C. (Thomas Cudworth). (1966) Liquid hydrogen sulphide as an ionising solvent. Part I. Base analogues and their neutralisation with hydrogen halides. Journal of the Chemical Society A: Inorganic, Physical, Theoretical . pp. 785-789. ISSN 0022-4944Full text not available from this repository.
Official URL: http://dx.doi.org/10.1039/J19660000785
Tetra-alkylammonium hydrogen sulphides, R4NSH, have been prepared. The salts co-ordinate hydrogen sulphide loosely at low temperatures; the hydrogen-bond energy is about 5 kcal. mole–1. Solutions of the salts in liquid hydrogen sulphide are strongly conducting, compared with solutions of amines and phosphines. A hydrogen dichloride salt was formed in the neutralisation of tetra-n-propylammonium hydrogen sulphide in liquid hydrogen sulphide. Similar reaction of hydrogen halides with tetra-alkylammonium halides in liquid hydrogen sulphide gave salts containing the anions, HCl2–, HBr2–, Hl2–, HBrCl–, and HCll–.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Divisions:||Faculty of Science > Chemistry|
|Journal or Publication Title:||Journal of the Chemical Society A: Inorganic, Physical, Theoretical|
|Publisher:||Royal Chemical Society|
|Page Range:||pp. 785-789|
Data sourced from: Butterworth, J. (1966). Report of the Vice Chancellor 1965-66. Coventry : University of Warwick.
Actions (login required)