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Liquid hydrogen sulphide as an ionising solvent. Part I. Base analogues and their neutralisation with hydrogen halides
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Cotton, J. D. and Waddington, T. C. (Thomas Cudworth) (1966) Liquid hydrogen sulphide as an ionising solvent. Part I. Base analogues and their neutralisation with hydrogen halides. Journal of the Chemical Society A: Inorganic, Physical, Theoretical . pp. 785-789. doi:10.1039/J19660000785 ISSN 0022-4944.
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Official URL: http://dx.doi.org/10.1039/J19660000785
Abstract
Tetra-alkylammonium hydrogen sulphides, R4NSH, have been prepared. The salts co-ordinate hydrogen sulphide loosely at low temperatures; the hydrogen-bond energy is about 5 kcal. mole–1. Solutions of the salts in liquid hydrogen sulphide are strongly conducting, compared with solutions of amines and phosphines. A hydrogen dichloride salt was formed in the neutralisation of tetra-n-propylammonium hydrogen sulphide in liquid hydrogen sulphide. Similar reaction of hydrogen halides with tetra-alkylammonium halides in liquid hydrogen sulphide gave salts containing the anions, HCl2–, HBr2–, Hl2–, HBrCl–, and HCll–.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Journal or Publication Title: | Journal of the Chemical Society A: Inorganic, Physical, Theoretical | ||||
Publisher: | Royal Chemical Society | ||||
ISSN: | 0022-4944 | ||||
Official Date: | 1966 | ||||
Dates: |
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Page Range: | pp. 785-789 | ||||
DOI: | 10.1039/J19660000785 | ||||
Status: | Peer Reviewed | ||||
Description: | Data sourced from: Butterworth, J. (1966). Report of the Vice Chancellor 1965-66. Coventry : University of Warwick. |
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