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Liquid hydrogen sulphide as an ionising solvent. Part II. Reactions of Lewis acids of boron with base analogues
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Cotton, J. D. and Waddington, T. C. (Thomas Cudworth) (1966) Liquid hydrogen sulphide as an ionising solvent. Part II. Reactions of Lewis acids of boron with base analogues. Journal of the Chemical Society A: Inorganic, Physical, Theoretical . pp. 789-793. doi:10.1039/J19660000789
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Official URL: http://dx.doi.org/10.1039/J19660000789
Abstract
Neutralisations of base analogues by volatile boron Lewis acids have been examined in liquid hydrogen sulphide. Salts containing the new anions BF3SH–, BCl3SH–, BBr3SH–, and BEt3SH– have been prepared. The reaction of diborane is more complicated but seems to proceed, at least initially, through the formation of the ion BH3,SH·BH3–, which subsequently loses hydrogen. The ions BF3SH– and BCl3SH– react with excess of boron trihalide to give tetrafluoroborate and tetrachloroborate ions, respectively.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science > Chemistry | ||||
| Journal or Publication Title: | Journal of the Chemical Society A: Inorganic, Physical, Theoretical | ||||
| Publisher: | Royal Chemical Society | ||||
| ISSN: | 0022-4944 | ||||
| Official Date: | 1966 | ||||
| Dates: |
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| Page Range: | pp. 789-793 | ||||
| DOI: | 10.1039/J19660000789 | ||||
| Status: | Peer Reviewed | ||||
| Description: | Data sourced from: Butterworth, J. (1966). Report of the Vice Chancellor 1965-66. Coventry : University of Warwick. |
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