Slavin, Stacy, Burns, James A., Haddleton, David M. and Remzi Becer, C. (2011) Synthesis of glycopolymers via click reactions. European Polymer Journal, Vol.47 (No.4). pp. 435-446. doi:10.1016/j.eurpolymj.2010.09.019

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Abstract

This mini-review describes recent work in the field of glycopolymer synthesis, with a focus on methods that have employed “click chemistry” and controlled polymerization methodology. A variety of carbohydrates with clickable groups such as azide, alkyne, and thiol moieties provide new routes to glycopolymers. Several studies use copper catalyzed azide-alkyne cycloaddition (CuAAC) reactions to synthesize glycomonomers or to incorporate carbohydrates into a clickable polymeric backbone. Alternatively, there are many thiol based click reactions which provide metal-free synthesis, which are discussed in details.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science, Engineering and Medicine > Science > Chemistry
Library of Congress Subject Headings (LCSH):	Organic compounds -- Synthesis, Polymers, Polymerization
Journal or Publication Title:	European Polymer Journal
Publisher:	Pergamon
ISSN:	00143057
Official Date:	April 2011
Dates:	Date Event April 2011 Published
Volume:	Vol.47
Number:	No.4
Page Range:	pp. 435-446
DOI:	10.1016/j.eurpolymj.2010.09.019
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Description:	Dedicated to Professor Nikos Hadjichristidis in recognition of his contribution to polymer science.
Funder:	European Union (EU), Lubrizol Corporation, Unilever (Firm), Engineering and Physical Sciences Research Council (EPSRC)

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