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Synthesis of glycopolymers via click reactions

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Slavin, Stacy, Burns, James A., Haddleton, David M. and Remzi Becer, C. (2011) Synthesis of glycopolymers via click reactions. European Polymer Journal, Vol.47 (No.4). pp. 435-446. doi:10.1016/j.eurpolymj.2010.09.019

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Official URL: http://dx.doi.org/10.1016/j.eurpolymj.2010.09.019

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Abstract

This mini-review describes recent work in the field of glycopolymer synthesis, with a focus on methods that have employed “click chemistry” and controlled polymerization methodology. A variety of carbohydrates with clickable groups such as azide, alkyne, and thiol moieties provide new routes to glycopolymers. Several studies use copper catalyzed azide-alkyne cycloaddition (CuAAC) reactions to synthesize glycomonomers or to incorporate carbohydrates into a clickable polymeric backbone. Alternatively, there are many thiol based click reactions which provide metal-free synthesis, which are discussed in details.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Library of Congress Subject Headings (LCSH): Organic compounds -- Synthesis, Polymers, Polymerization
Journal or Publication Title: European Polymer Journal
Publisher: Pergamon
ISSN: 00143057
Official Date: April 2011
Dates:
DateEvent
April 2011Published
Volume: Vol.47
Number: No.4
Page Range: pp. 435-446
DOI: 10.1016/j.eurpolymj.2010.09.019
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Description:

Dedicated to Professor Nikos Hadjichristidis in recognition of his contribution to polymer science.

Funder: European Union (EU), Lubrizol Corporation, Unilever (Firm), Engineering and Physical Sciences Research Council (EPSRC)

Data sourced from Thomson Reuters' Web of Knowledge

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