Skip to content Skip to navigation
University of Warwick
  • Study
  • |
  • Research
  • |
  • Business
  • |
  • Alumni
  • |
  • News
  • |
  • About

University of Warwick
Publications service & WRAP

Highlight your research

  • WRAP
    • Home
    • Search WRAP
    • Browse by Warwick Author
    • Browse WRAP by Year
    • Browse WRAP by Subject
    • Browse WRAP by Department
    • Browse WRAP by Funder
    • Browse Theses by Department
  • Publications Service
    • Home
    • Search Publications Service
    • Browse by Warwick Author
    • Browse Publications service by Year
    • Browse Publications service by Subject
    • Browse Publications service by Department
    • Browse Publications service by Funder
  • Help & Advice
University of Warwick

The Library

  • Login
  • Admin

Copper-catalyzed rearrangement of oximes into primary amides

Tools
- Tools
+ Tools

Sharma, Sumeet K., Bishopp, Simon D., Liana Allen, C., Lawrence, R. (Ruth), Bamford, Mark J., Lapkin, Alexei, Plucinski, Pawel K., Watson, Robert J. and Williams, Jonathan M. J. (2011) Copper-catalyzed rearrangement of oximes into primary amides. Tetrahedron Letters, Vol.52 (No.33). pp. 4252-4255. doi:10.1016/j.tetlet.2011.05.129 ISSN 0040-4039.

Research output not available from this repository.

Request-a-Copy directly from author or use local Library Get it For Me service.

Official URL: http://dx.doi.org/10.1016/j.tetlet.2011.05.129

Request Changes to record.

Abstract

The atom-efficient and cost-effective rearrangement of oximes into primary amides is catalyzed by simple copper salts. The use of homogeneous Cu(OAc)2 (1–2 mol %) was found to be effective for this transformation at 80 °C. The reaction was successful with either conventional or microwave heating. CuO and CuO/ZnO on activated carbon provided a competent reuseable heterogeneous catalyst which could be used in a batch process or in flow. Copper salts are much cheaper than the precious metals previously used for this rearrangement, and the reaction conditions are milder than those reported.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
T Technology > TP Chemical technology
Divisions: Faculty of Science, Engineering and Medicine > Engineering > Engineering
Library of Congress Subject Headings (LCSH): Amides, Oximes, Copper, Copper salts, Rearrangements (Chemistry), Metal catalysts
Journal or Publication Title: Tetrahedron Letters
Publisher: Pergamon
ISSN: 0040-4039
Official Date: 17 August 2011
Dates:
DateEvent
17 August 2011Published
Volume: Vol.52
Number: No.33
Number of Pages: 4
Page Range: pp. 4252-4255
DOI: 10.1016/j.tetlet.2011.05.129
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Engineering and Physical Sciences Research Council (EPSRC), GlaxoSmithKline (GSK)
Grant number: EP/G028141/1 (EPSRC)

Data sourced from Thomson Reuters' Web of Knowledge

Request changes or add full text files to a record

Repository staff actions (login required)

View Item View Item
twitter

Email us: wrap@warwick.ac.uk
Contact Details
About Us