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An unexpected directing effect in the asymmetric transfer hydrogenation of α,α-Disubstituted ketones
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Soni, Rina, Collinson, John-Michael, Clarkson, Guy J. and Wills, Martin (2011) An unexpected directing effect in the asymmetric transfer hydrogenation of α,α-Disubstituted ketones. Organic Letters, 13 (16). pp. 4304-4307. doi:10.1021/ol201643v
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Official URL: http://dx.doi.org/10.1021/ol201643v
Abstract
alpha,alpha-Disubstituted ketones containing an aromatic ring or alkene are reduced in high enantiomeric excess using an asymmetric transfer hydrogenation catalyst. The sense of reduction indicates that the unsaturated region of the ketone adopts a position adjacent to the Ru-bound eta(6)-arene ring in the reduction transition state.
| Item Type: | Journal Article | ||||||||
|---|---|---|---|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||||||
| Divisions: | Faculty of Science > Chemistry | ||||||||
| Library of Congress Subject Headings (LCSH): | Hydrogenation, Carbonyl compounds, Ketones, Reduction (Chemistry), Catalysis | ||||||||
| Journal or Publication Title: | Organic Letters | ||||||||
| Publisher: | American Chemical Society | ||||||||
| ISSN: | 1523-7060 | ||||||||
| Official Date: | 14 July 2011 | ||||||||
| Dates: |
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| Volume: | 13 | ||||||||
| Number: | 16 | ||||||||
| Page Range: | pp. 4304-4307 | ||||||||
| DOI: | 10.1021/ol201643v | ||||||||
| Status: | Peer Reviewed | ||||||||
| Publication Status: | Published | ||||||||
| Access rights to Published version: | Restricted or Subscription Access |
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