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Solution and mechanochemical syntheses, and spectroscopic and structural studies in the silver(i) (bi-)carbonate : triphenylphosphine system

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Bowmaker, Graham A., Effendy, Dr., Hanna, John V., Healy, Peter C., King, Scott P., Pettinari, Claudio, Skelton, Brian W. and White, Allan H. (2011) Solution and mechanochemical syntheses, and spectroscopic and structural studies in the silver(i) (bi-)carbonate : triphenylphosphine system. Dalton Transactions, Vol.40 (No.27). pp. 7210-7218. doi:10.1039/c1dt10416k

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Official URL: http://dx.doi.org/10.1039/c1dt10416k

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Abstract

Syntheses of a number of adducts of silver(I) (bi-)carbonate with triphenylphosphine, both mechanochemically, and from solution, are described, together with their infra-red spectra, (31)P CP MAS NMR and crystal structures. Ag(HCO(3)):PPh(3) (1 : 4) has been isolated in the ionic form [Ag(PPh(3))(4)(HCO(3))center dot 2EtOH center dot 3H(2)O. Ag(2)CO(3):PPh(3) (1 : 4) forms a binuclear neutral molecule [(Ph(3)P)(2)Ag(O,mu-O'center dot CO)Ag(PPh(3))(2)](center dot 2H(2)O), while Ag(HCO(3)):PPh(3) (1 : 2) has been isolated in both mononuclear and binuclear forms: [(Ph(3)P)(2)Ag(O(2)COH)] and [(Ph(3)P)(2)Ag(mu-O center dot CO center dot OH)(2)Ag(PPh(3))(2)] (both unsolvated). A more convenient method for the preparation of the previously reported copper(I) complex [(Ph(3P))(2)Cu(HCO(3))] is also reported.

Item Type: Journal Article
Subjects: Q Science > QC Physics
Q Science > QD Chemistry
Divisions: Faculty of Science > Physics
Library of Congress Subject Headings (LCSH): Infrared spectra, Mechanical chemistry, Nuclear magnetic resonance spectroscopy, Carbonates
Journal or Publication Title: Dalton Transactions
Publisher: Royal Society of Chemistry
ISSN: 1477-9226
Official Date: 21 July 2011
Dates:
DateEvent
21 July 2011Published
Volume: Vol.40
Number: No.27
Page Range: pp. 7210-7218
DOI: 10.1039/c1dt10416k
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Engineering and Physical Sciences Research Council (EPSRC), University of Warwick, Advantage West Midlands (AWM), European Regional Development Fund (ERDF), Università di Camerino

Data sourced from Thomson Reuters' Web of Knowledge

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