The Library
Solution and mechanochemical syntheses, and spectroscopic and structural studies in the silver(i) (bi-)carbonate : triphenylphosphine system
Tools
Bowmaker, Graham A., Effendy, Dr., Hanna, John V., Healy, Peter C., King, Scott P., Pettinari, Claudio, Skelton, Brian W. and White, Allan H. (2011) Solution and mechanochemical syntheses, and spectroscopic and structural studies in the silver(i) (bi-)carbonate : triphenylphosphine system. Dalton Transactions, Vol.40 (No.27). pp. 7210-7218. doi:10.1039/c1dt10416k ISSN 1477-9226.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Official URL: http://dx.doi.org/10.1039/c1dt10416k
Abstract
Syntheses of a number of adducts of silver(I) (bi-)carbonate with triphenylphosphine, both mechanochemically, and from solution, are described, together with their infra-red spectra, (31)P CP MAS NMR and crystal structures. Ag(HCO(3)):PPh(3) (1 : 4) has been isolated in the ionic form [Ag(PPh(3))(4)(HCO(3))center dot 2EtOH center dot 3H(2)O. Ag(2)CO(3):PPh(3) (1 : 4) forms a binuclear neutral molecule [(Ph(3)P)(2)Ag(O,mu-O'center dot CO)Ag(PPh(3))(2)](center dot 2H(2)O), while Ag(HCO(3)):PPh(3) (1 : 2) has been isolated in both mononuclear and binuclear forms: [(Ph(3)P)(2)Ag(O(2)COH)] and [(Ph(3)P)(2)Ag(mu-O center dot CO center dot OH)(2)Ag(PPh(3))(2)] (both unsolvated). A more convenient method for the preparation of the previously reported copper(I) complex [(Ph(3P))(2)Cu(HCO(3))] is also reported.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QC Physics Q Science > QD Chemistry |
||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Physics | ||||
Library of Congress Subject Headings (LCSH): | Infrared spectra, Mechanical chemistry, Nuclear magnetic resonance spectroscopy, Carbonates | ||||
Journal or Publication Title: | Dalton Transactions | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1477-9226 | ||||
Official Date: | 21 July 2011 | ||||
Dates: |
|
||||
Volume: | Vol.40 | ||||
Number: | No.27 | ||||
Page Range: | pp. 7210-7218 | ||||
DOI: | 10.1039/c1dt10416k | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC), University of Warwick, Advantage West Midlands (AWM), European Regional Development Fund (ERDF), Università di Camerino |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |