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Solution and mechanochemical syntheses, and spectroscopic and structural studies in the silver(i) (bi-)carbonate : triphenylphosphine system
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Bowmaker, Graham A., Effendy, Dr., Hanna, John V., Healy, Peter C., King, Scott P., Pettinari, Claudio, Skelton, Brian W. and White, Allan H.. (2011) Solution and mechanochemical syntheses, and spectroscopic and structural studies in the silver(i) (bi-)carbonate : triphenylphosphine system. Dalton Transactions, Vol.40 (No.27). pp. 7210-7218. ISSN 1477-9226
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Official URL: http://dx.doi.org/10.1039/c1dt10416k
Abstract
Syntheses of a number of adducts of silver(I) (bi-)carbonate with triphenylphosphine, both mechanochemically, and from solution, are described, together with their infra-red spectra, (31)P CP MAS NMR and crystal structures. Ag(HCO(3)):PPh(3) (1 : 4) has been isolated in the ionic form [Ag(PPh(3))(4)(HCO(3))center dot 2EtOH center dot 3H(2)O. Ag(2)CO(3):PPh(3) (1 : 4) forms a binuclear neutral molecule [(Ph(3)P)(2)Ag(O,mu-O'center dot CO)Ag(PPh(3))(2)](center dot 2H(2)O), while Ag(HCO(3)):PPh(3) (1 : 2) has been isolated in both mononuclear and binuclear forms: [(Ph(3)P)(2)Ag(O(2)COH)] and [(Ph(3)P)(2)Ag(mu-O center dot CO center dot OH)(2)Ag(PPh(3))(2)] (both unsolvated). A more convenient method for the preparation of the previously reported copper(I) complex [(Ph(3P))(2)Cu(HCO(3))] is also reported.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QC Physics Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Physics |
| Library of Congress Subject Headings (LCSH): | Infrared spectra, Mechanical chemistry, Nuclear magnetic resonance spectroscopy, Carbonates |
| Journal or Publication Title: | Dalton Transactions |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1477-9226 |
| Official Date: | 21 July 2011 |
| Volume: | Vol.40 |
| Number: | No.27 |
| Page Range: | pp. 7210-7218 |
| Identification Number: | 10.1039/c1dt10416k |
| Status: | Peer Reviewed |
| Publication Status: | Published |
| Access rights to Published version: | Restricted or Subscription Access |
| Funder: | Engineering and Physical Sciences Research Council (EPSRC), University of Warwick, Advantage West Midlands (AWM), European Regional Development Fund (ERDF), Università di Camerino |
| URI: | http://wrap.warwick.ac.uk/id/eprint/38663 |
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