Ferreira, Julien, Syrett, Jay A., Whittaker, Michael R., Haddleton, David M., Davis, Thomas P. (Thomas Paul), 1960- and Boyer, Cyrille. (2011) Optimizing the generation of narrow polydispersity ‘arm-first’ star polymers made using RAFT polymerization. Polymer Chemistry, Vol.2 (No.8). pp. 1671-1677. ISSN 1759-9954

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Abstract

In this article, the synthesis of well-defined, narrow polydispersity (PDI < 1.2) star polymers via RAFT polymerisation is detailed. An 'arm-first' method is described using a crosslinked nanogel core. The synthetic conditions and variables were thoroughly investigated and optimised so that nearly quantitative arm incorporation was found to occur. The parameters studied included polymerization time, the arm molecular weight, and the nature of the solvent and cross-linker.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry T Technology > TP Chemical technology
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Polymerization, Polyethylene oxide, Cyclodextrins, Block copolymers, Drug delivery systems, Rheology
Journal or Publication Title:	Polymer Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1759-9954
Date:	2011
Volume:	Vol.2
Number:	No.8
Page Range:	pp. 1671-1677
Identification Number:	10.1039/c1py00102g
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Australian Research Council (ARC)
Grant number:	DP1092640 (ARC), DP110104251 (ARC)
References:	1 B. M. Erwin, M. Cloitre, M. Gauthier and D. Vlassopoulos, Soft Matter, 2010, 6, 2825–2833. 2 S. Coppola, N. Grizzuti, G. Floudas and D. Vlassopoulos, J. Rheol., 2007, 51, 1007–1025. 3 T. K. Goh, K. D. Coventry, A. Blencowe and G. G. Qiao, Polymer, 2008, 49, 5095–5104. 4 M. Sugimoto, T. Koizumi, T. Taniguchi, K. Koyama, K. Saito, D. Nonokawa and T. Morita, J. Polym. Sci., Part B: Polym. Phys., 2009, 47, 2226–2237. 5 M. E. Fox, F. C. Szoka and J. M. J. Frechet, Acc. Chem. Res., 2009, 42, 1141–1151. 6 C. Boyer, V. Bulmus, T. P. Davis, V. Ladmiral, J. Liu and S. Perrier, Chem. Rev., 2009, 109, 5402–5436. 7 J. T. Wiltshire and G. G. Qiao, Aust. J. Chem., 2007, 60, 699–705. 8 J.-H. Ryu, R. T. Chacko, S. Jiwpanich, S. Bickerton, R. P. Babu and S. Thayumanavan, J. Am. Chem. Soc., 2010, 132, 17227–17235. 9 V. Rodionov, H. Gao, S. Scroggins, D. A. Unruh, A.-J. Avestro and J. M. J. Frechet, J. Am. Chem. Soc., 2010, 132, 2570–2572. 10 Q. Zhao, S.-J. Liu and W. Huang, Macromol. Chem. Phys., 2009, 210, 1580–1590. 11 A. L. Kanibolotsky, I. F. Perepichka and P. J. Skabara, Chem. Soc. Rev., 2010, 39, 2695–2728. 12 N. Hadjichristidis, H. Iatrou, M. Pitsikalis and J. Mays, Prog. Polym. Sci., 2006, 31, 1068–1132. 13 K. Khanna, S. Varshney and A. Kakkar, Polym. Chem., 2010, 1, 1171–1185. 14 S. Aoshima and S. Kanaoka, Chem. Rev., 2009, 109, 5245–5287. 15 K. Matyjaszewski and N. V. Tsarevsky, Nat. Chem., 2009, 1, 276–288. 16 W. Li and K. Matyjaszewski, Macromol. Rapid Commun., 2011, 32, 74–81. 17 H. Gao and K. Matyjaszewski, Prog. Polym. Sci., 2009, 34, 317–350. 18 G. Deng, M. Cao, J. Huang, L. He and Y. Chen, Polymer, 2005, 46, 5698–5701. 19 M. Ouchi, T. Terashima and M. Sawamoto, Acc. Chem. Res., 2008, 41, 1120–1132. 20 A. Blencowe, J. F. Tan, T. K. Goh and G. G. Qiao, Polymer, 2009, 50, 5–32. 21 S. Hou, E. L. Chaikof, D. Taton and Y. Gnanou, Macromolecules, 2003, 36, 3874–3881. 22 C. Boyer, M. H. Stenzel and T. P. Davis, J. Polym. Sci., Part A: Polym. Chem., 2011, 49, 551–595. 23 G. Moad, Aust. J. Chem., 2006, 59, 661–662. 24 H. Chaffey-Millar, M. H. Stenzel, T. P. Davis, M. L. Coote and C. Barner-Kowollik, Macromolecules, 2006, 39, 6406–6419. 25 M. H. Stenzel and T. P. Davis, J. Polym. Sci., Part A: Polym. Chem., 2002, 40, 4498–4512. 26 G. Moad, Y. K. Chong, A. Postma, E. Rizzardo and S. H. Thang, Polymer, 2005, 46, 8458–8468. 27 K. Ranganathan, R. Deng, R. K. Kainthan, C.Wu, D. E. Brooks and J. N. Kizhakkedathu, Macromolecules, 2008, 41, 4226–4234. 28 D. Taton, J.-F. Baussard, L. Dupayage, Y. Gnanou, M. Destarac, C. Mignaud and C. Pitois, in Controlled/Living Radical Polymerization, American Chemical Society, 2006, vol. 944, pp. 578–594. 29 A. Dureault, D. Taton, M. Destarac, F. Leising and Y. Gnanou, Macromolecules, 2004, 37, 5513–5519. 30 G. Moad, E. Rizzardo and S. H. Thang, Acc. Chem. Res., 2008, 41, 1133–1142. 31 S. A. Bencherif, H. Gao, A. Srinivasan, D. J. Siegwart, J. O. Hollinger, N. R. Washburn and K. Matyjaszewski, Biomacromolecules, 2009, 10, 1795–1803. 32 H. Y. Cho, H. Gao, A. Srinivasan, J. Hong, S. A. Bencherif, D. J. Siegwart, H.-j. Paik, J. O. Hollinger and K. Matyjaszewski, Biomacromolecules, 2010, 11, 2199–2203. 33 C. Barner-Kowollik, T. P. Davis and M. H. Stenzel, Aust. J. Chem., 2006, 59, 719–727. 34 D. Boschmann, M.M€anz, M. G. Fr€ohlich, G. Zifferer and P. Vana, in Controlled/Living Radical Polymerization: Progress in RAFT, DT, NMP & OMRP, American Chemical Society, 2009, vol. 1024, pp. 217–232. 35 M. G. Frohlich, P. Vana and G. Zifferer, J. Chem. Phys., 2007, 127, 164906–164907. 36 M. G. Fr€ohlich, M. M. Nardai, N. F€orster, P. Vana and G. Zifferer, Polymer, 2010, 51, 5122–5134. 37 E. Setijadi, L. Tao, J. Liu, Z. Jia, C. Boyer and T. P. Davis, Biomacromolecules, 2009, 10, 2699–2707. 38 H. T. Lord, J. F. Quinn, S. D. Angus,M. R.Whittaker,M. H. Stenzel and T. P. Davis, J. Mater. Chem., 2003, 13, 2819–2824. 39 J. Liu, L. Tao, J. Xu, Z. Jia, C. Boyer and T. P. Davis, Polymer, 2009, 50, 4455–4463. 40 H. Hussain, B. H. Tan, C. S. Gudipati, Y. Xaio, Y. Liu, T. P. Davis and C. B. He, J. Polym. Sci., Part A: Polym. Chem., 2008, 46, 7287– 7298. 41 J. F. Quinn, R. P. Chaplin and T. P. Davis, J. Polym. Sci., Part A: Polym. Chem., 2002, 40, 2956–2966. 42 M. H. Stenzel-Rosenbaum, T. P. Davis, V. Chen and A. G. Fane, Macromolecules, 2001, 34, 5433–5438. 43 M. H. Stenzel, T. P. Davis and C. Barner-Kowollik, Chem. Commun., 2004, 1546–1547. 44 J. Bernard, X. Hao, T. P. Davis, C. Barner-Kowollik and M. H. Stenzel, Biomacromolecules, 2005, 7, 232–238. 45 L. Viau, M. Even, O. Maury, D. M. Haddleton and H. Le Bozec, C. R. Chim., 2005, 8, 1298–1307. 46 A. P. Narrainen, S. Pascual and D. M. Haddleton, J. Polym. Sci., Part A: Polym. Chem., 2002, 40, 439–450. 47 K. Ohno, B. Wong and D. M. Haddleton, J. Polym. Sci., Part A: Polym. Chem., 2001, 39, 2206–2214. 48 D. M. Haddleton, R. Edmonds, A. M. Heming, E. J. Kelly and D. Kukulj, New J. Chem., 1999, 23, 477–479. 49 B. S. Sumerlin and A. P. Vogt, Macromolecules, 2009, 43, 1–13. 50 P. L. Golas and K. Matyjaszewski, Chem. Soc. Rev., 2010, 39, 1338– 1354. 51 J. A. Johnson, M. G. Finn, J. T. Koberstein and N. J. Turro, Macromol. Rapid Commun., 2008, 29, 1421. 52 J. W. Chan, B. Yu, C. E. Hoyle and A. B. Lowe, Polymer, 2009, 50, 3158–3168. 53 J. W. Chan, B. Yu, C. E. Hoyle and A. B. Lowe, Chem. Commun., 2008, 4959–4961. 54 J. F. Tan, A. Blencowe, T. K. Goh, I. T. M. Dela Cruz and G. G. Qiao, Macromolecules, 2009, 42, 4622–4631. 55 M. Spiniello, A. Blencowe and G. G. Qiao, J. Polym. Sci., Part A: Polym. Chem., 2008, 46, 2422–2432. 56 T. K. Goh, A. P. Sulistio, A. Blencowe, J. W. Johnson and G. G. Qiao, Macromolecules, 2007, 40, 7819–7826. 57 J. A. Syrett, D. M. Haddleton, M. R. Whittaker, T. P. Davis and C. Boyer, Chem. Commun., 2011, 47, 1449–1451. 58 C. Boyer, V. Bulmus and T. P. Davis, Macromol. Rapid Commun., 2009, 30, 493–497. 59 J. Rosselgong, S. P. Armes, W. Barton and D. Price, Macromolecules, 2009, 42, 5919–5924. 60 J. Rosselgong, S. P. Armes, W. R. S. Barton and D. Price, Macromolecules, 2010, 43, 2145–2156.
URI:	http://wrap.warwick.ac.uk/id/eprint/38703

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