Barford, W. (William), Ball, Robin and Nex, C. M. M.. (1986) A non-equilibrium configuration theory of polyelectrolyte adsorption. Journal of the Chemical Society, Faraday Transactions 1, vol.82 (No.10). pp. 3233-3244. ISSN 0300-9589

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Abstract

The adsorption of polyelectrolytes is poorly understood, with experiments suggesting irreversible behaviour beyond the scope of equilibrium theories. We propose a new sequential adsorption theory which has quantitatively different predictions from the equilibrium case. In particular, the predicted threshold value of the surface concentration at which no more polymer can adsorb is much smaller and thus there are more likely to be extended states of adsorbed polymer.

Item Type:	Journal Article
Subjects:	Q Science > QC Physics Q Science > QD Chemistry
Divisions:	Faculty of Science > Physics
Library of Congress Subject Headings (LCSH):	Nonequilibrium statistical mechanics, Adsorption, Polyelectrolytes, Polymers -- Absorption and adsorption
Journal or Publication Title:	Journal of the Chemical Society, Faraday Transactions 1
Publisher:	Royal Society of Chemistry
ISSN:	0300-9589
Official Date:	1986
Volume:	vol.82
Number:	No.10
Page Range:	pp. 3233-3244
Identification Number:	10.1039/F19868203233
Status:	Peer Reviewed
Publication Status:	Published
URI:	http://wrap.warwick.ac.uk/id/eprint/39413

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