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A non-equilibrium configuration theory of polyelectrolyte adsorption
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Barford, W. (William), Ball, Robin and Nex, C. M. M.. (1986) A non-equilibrium configuration theory of polyelectrolyte adsorption. Journal of the Chemical Society, Faraday Transactions 1, vol.82 (No.10). pp. 3233-3244. ISSN 0300-9589
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Official URL: http://dx.doi.org/10.1039/F19868203233
Abstract
The adsorption of polyelectrolytes is poorly understood, with experiments suggesting irreversible behaviour beyond the scope of equilibrium theories. We propose a new sequential adsorption theory which has quantitatively different predictions from the equilibrium case. In particular, the predicted threshold value of the surface concentration at which no more polymer can adsorb is much smaller and thus there are more likely to be extended states of adsorbed polymer.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QC Physics Q Science > QD Chemistry |
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| Divisions: | Faculty of Science > Physics | ||||
| Library of Congress Subject Headings (LCSH): | Nonequilibrium statistical mechanics, Adsorption, Polyelectrolytes, Polymers -- Absorption and adsorption | ||||
| Journal or Publication Title: | Journal of the Chemical Society, Faraday Transactions 1 | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 0300-9589 | ||||
| Official Date: | 1986 | ||||
| Dates: |
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| Volume: | vol.82 | ||||
| Number: | No.10 | ||||
| Page Range: | pp. 3233-3244 | ||||
| Identification Number: | 10.1039/F19868203233 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| URI: | http://wrap.warwick.ac.uk/id/eprint/39413 |
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