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V2O3(0001) surface termination : phase equilibrium
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Window, A. J. (Amanda J.), Hentz, A., Sheppard, Daniel Crispin, Parkinson, G. S., Niehus, H., Ahlbehrendt, D., Noakes, T. C. Q., Bailey, P. and Woodruff, D. P.. (2011) V2O3(0001) surface termination : phase equilibrium. Physical Review Letters, Vol.107 (No.1). 016105. ISSN 0031-9007
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Official URL: http://dx.doi.org/10.1103/PhysRevLett.107.016105
Abstract
Complementary but independent medium-energy and low-energy ion scattering studies of the (0001) surfaces of V2O3 films grown on Pd(111), Au(111) and Cu3Au(100) reveal a reconstructed full O3-layer termination creating a VO2 surface trilayer. This structure is fully consistent with previous calculations based on thermodynamic equilibrium at the surface during growth, but contrasts with previous suggestions that the surface termination comprises a complete monolayer of vanadyl (V=O) species.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QC Physics Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Physics |
| Library of Congress Subject Headings (LCSH): | Vanadium oxide -- Surfaces |
| Journal or Publication Title: | Physical Review Letters |
| Publisher: | American Physical Society |
| ISSN: | 0031-9007 |
| Date: | 2011 |
| Volume: | Vol.107 |
| Number: | No.1 |
| Number of Pages: | 4 |
| Page Range: | 016105 |
| Identification Number: | 10.1103/PhysRevLett.107.016105 |
| Status: | Peer Reviewed |
| Publication Status: | Published |
| Access rights to Published version: | Restricted or Subscription Access |
| Funder: | Deutsche Forschungsgemeinschaft (DFG), Engineering and Physical Sciences Research Council (EPSRC) |
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| URI: | http://wrap.warwick.ac.uk/id/eprint/39459 |
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