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High-resolution x-ray diffraction study of single crystals of lead zirconate titanate

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Gorfman, S., Keeble, Dean Samuel, Glazer, A. M. (Anthony Michael), Long, X., Xie, Y. (Yuehong), Ye, Z. -G., Collins, Stephen P. and Thomas, Pam A. (2011) High-resolution x-ray diffraction study of single crystals of lead zirconate titanate. Physical Review B (Condensed Matter and Materials Physics), Vol.84 (No.2). Article 020102(R). doi:10.1103/PhysRevB.84.020102 ISSN 1098-0121.

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Official URL: http://dx.doi.org/10.1103/PhysRevB.84.020102

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Abstract

The symmetry of single-crystal piezoelectric PbZr1-xTixO3, with x≈0.31 and x≈0.46, has been investigated by high-resolution x-ray diffraction, both at room temperature and up to and above the Curie temperature. Reciprocal space maps around a selection of Bragg reflections were collected and self-consistent patterns showing Bragg splittings were observed. The analysis of the separation of peaks from different twin domains provides precise information on PbZr1-xTixO3 symmetry when approaching the morphotropic phase boundary at x=0.48 from the zirconium-rich side.

Item Type: Journal Article
Subjects: Q Science > QC Physics
Q Science > QD Chemistry
Divisions: Faculty of Science, Engineering and Medicine > Science > Physics
Library of Congress Subject Headings (LCSH): X-rays -- Diffraction, Crystals, Lead zirconate titanate, Piezoelectricity
Journal or Publication Title: Physical Review B (Condensed Matter and Materials Physics)
Publisher: American Physical Society
ISSN: 1098-0121
Official Date: 2011
Dates:
DateEvent
2011Published
Volume: Vol.84
Number: No.2
Number of Pages: 4
Page Range: Article 020102(R)
DOI: 10.1103/PhysRevB.84.020102
Status: Peer Reviewed
Publication Status: Published
Funder: Engineering and Physical Sciences Research Council (EPSRC), United States. Office of Naval Research (ONR), Natural Sciences and Engineering Research Council of Canada (NSERC)
Grant number: N0014-06-1-0166 (ONR)

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