Howson, Suzanne E. and Scott, Peter, 1965 Dec. 10-. (2011) Approaches to the synthesis of optically pure helicates. Dalton Transactions, Vol.40 (No. 40). article no.10268. ISSN 1477-9226

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Abstract

Methods by which helical bimetallic assemblies may be accessed as single isomers are described and reviewed. While there are a number of notable successes, the conclusion is made that no existing approach satisfies the criteria which will allow these fascinating compounds to emerge from the synthetic research laboratory environment to practical application in e.g. healthcare. For this to be achieved the compounds must be optically pure and non-racemising, soluble and chemically stable in water, readily available on a large scale, chemically diverse and synthetically robust.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Self-assembly (Chemistry), Chirality
Journal or Publication Title:	Dalton Transactions
Publisher:	Royal Society of Chemistry
ISSN:	1477-9226
Date:	2011
Volume:	Vol.40
Number:	No. 40
Page Range:	article no.10268
Identification Number:	10.1039/c1dt11423a
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
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URI:	http://wrap.warwick.ac.uk/id/eprint/39550

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