Hansell, Claire F., Espeel, Pieter, Stamenović, Milan M., Barker, Ian A., Dove, Andrew P., Du Prez, Filip E. and O'Reilly, Rachel K.. (2011) Additive-free clicking for polymer functionalization and coupling by tetrazine–norbornene chemistry. Journal of the American Chemical Society, Vol.133 (No.35). pp. 13828-13831. ISSN 0002-7863

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Abstract

Herein we report the use of a tetrazine-norbornene inverse electron demand Diels–Alder conjugation applied to polymer end-functionalization and polymer–polymer coupling. The reaction was found to be applicable to polymer–polymer coupling, as judged by SEC, DOSY NMR, and LCxSEC analyses, giving diblock copolymers by merely mixing the constituent homopolymers together under ambient conditions, using no catalyst, additive, or external stimulus.

Item Type:	Journal Article
Divisions:	Faculty of Science > Chemistry
Journal or Publication Title:	Journal of the American Chemical Society
Publisher:	American Chemical Society
ISSN:	0002-7863
Official Date:	2011
Volume:	Vol.133
Number:	No.35
Page Range:	pp. 13828-13831
Identification Number:	10.1021/ja203957h
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Engineering and Physical Sciences Research Council (EPSRC), University of Warwick, Ghent University, P2M ESF
URI:	http://wrap.warwick.ac.uk/id/eprint/39808

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