Additive-free clicking for polymer functionalization and coupling by tetrazine–norbornene chemistry
Hansell, Claire F., Espeel, Pieter, Stamenović, Milan M., Barker, Ian A., Dove, Andrew P., Du Prez, Filip E. and O'Reilly, Rachel K.. (2011) Additive-free clicking for polymer functionalization and coupling by tetrazine–norbornene chemistry. Journal of the American Chemical Society, Vol.133 (No.35). pp. 13828-13831. ISSN 0002-7863Full text not available from this repository.
Official URL: http://dx.doi.org/10.1021/ja203957h
Herein we report the use of a tetrazine-norbornene inverse electron demand Diels–Alder conjugation applied to polymer end-functionalization and polymer–polymer coupling. The reaction was found to be applicable to polymer–polymer coupling, as judged by SEC, DOSY NMR, and LCxSEC analyses, giving diblock copolymers by merely mixing the constituent homopolymers together under ambient conditions, using no catalyst, additive, or external stimulus.
|Item Type:||Journal Article|
|Divisions:||Faculty of Science > Chemistry|
|Journal or Publication Title:||Journal of the American Chemical Society|
|Publisher:||American Chemical Society|
|Page Range:||pp. 13828-13831|
|Access rights to Published version:||Restricted or Subscription Access|
|Funder:||Engineering and Physical Sciences Research Council (EPSRC), University of Warwick, Ghent University, P2M ESF|
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