Sullivan, Paul J., Duraud, Amelie, Hancox, I. (Ian), Beaumont, Nicola, Mirri, Giorgio, Tucker, James H. R., Hatton, Ross A., Shipman, Michael and Jones, T. S. (Tim S.). (2011) Halogenated boron subphthalocyanines as light harvesting electron acceptors in organic photovoltaics. Advanced Energy Materials, Vol.1 (No.3). pp. 352-355. ISSN 1614-6832

Full text not available from this repository.

Abstract

By tuning the frontier orbital energies through selective halogenation of the periphery of the organic framework, new light harvesting electron acceptors based on boron subphthalocyanine chloride (SubPc) have been made. Planar heterojunction organic photovoltaics made using a Cl6-SubPc acceptor deliver an exceptionally high open-circuit voltage (∼1.3 V), good power conversion efficiency (∼2.7%) and improved operational stability in comparison to similar devices made using C60 as the acceptor material.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry T Technology > TK Electrical engineering. Electronics Nuclear engineering
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Electrophiles, Photovoltaic power generation, Halogenation, Boron
Journal or Publication Title:	Advanced Energy Materials
Publisher:	Wiley - V C H Verlag GmbH & Co. KGaA
ISSN:	1614-6832
Date:	May 2011
Volume:	Vol.1
Number:	No.3
Page Range:	pp. 352-355
Identification Number:	10.1002/aenm.201100036
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Engineering and Physical Sciences Research Council (EPSRC), Royal Academy of Engineering (Great Britain)
References:	[ 1 ] D. Wynands , M. Levichkova , M. Riede , M. Pfeiffer , P. Baeuerle , R. Rentenberger , P. Denner , K. Leo , J. Appl. Phys. 2010 , 107 , 014517 . [ 2 ] P. Sullivan , S. Heutz , S. M. Schultes , T. S. Jones , Appl. Phys. Lett. 2004 , 84 , 1210 . [ 3 ] J. G. Xue , B. P. Rand , S. Uchida , S. R. Forrest , J. Appl. Phys. 2005 , 98 , 124903 . [ 4 ] N. Li , S. R. Forrest , Appl. Phys. Lett. 2009 , 95 , 123309 . [ 5 ] P. Sullivan , T. S. Jones , A. J. Ferguson , S. Heutz , Appl. Phys. Lett. 2007 , 91 , 233114 . [ 6 ] W. J. Potscavage , A. Sharma , B. Kippelen , Acc. Chem. Res. 2009 , 42 , 1758 . [ 7 ] S. Y. Wang , E. I. Mayo , M. D. Perez , L. Griffe , G. D. Wei , P. I. Djurovich , S. R. Forrest , M. E. Thompson , Appl. Phys. Lett. 2009 , 94 , 233304 . [ 8 ] M. O. Reese , A. M. Nardes , B. L. Rupert , R. E. Larsen , D. C. Olson , M. T. Lloyd , S. E. Shaheen , D. S. Ginley , G. Rumbles , N. Kopidakis , Adv. Funct. Mater. 2010 , 20 , 3476 . [ 9 ] R. Lessmann , Z. Hong , S. Scholz , B. Maennig , M. K. Riede , K. Leo , Org. Electron. 2010 , 11 , 539 . [ 10 ] J. C. Bijleveld , R. A. M. Verstrijden , M. M. Wienk , R. A. J. Janssen , Appl. Phys. Lett. 2010 , 97 , 073304 . [ 11 ] B. P. Rand , D. P. Burk , S. R. Forrest , Phys. Rev. B 2007 , 75 , 115327 . [ 12 ] H. Peisert , M. Knupfer , T. Schwieger , G. G. Fuentes , D. Olligs , J. Fink , T. Schmidt , J. Appl. Phys. 2003 , 93 , 9683 . [ 13 ] M. L. Tang , J. H. Oh , A. D. Reichardt , Z. N. Bao , J. Am. Chem. Soc. 2009 , 131 , 3733 . [ 14 ] M. Knupfer , H. Peisert , Phys. Status Solidi A 2004 , 201 , 1055 . [ 15 ] X. R. Tong , B. E. Lassiter , S. R. Forrest , Org. Electron. 2010 , 11 , 705 . [ 16 ] K. L. Mutolo , E. I. Mayo , B. P. Rand , S. R. Forrest , M. E. Thompson , J. Am. Chem. Soc. 2006 , 128 , 8108 . [ 17 ] a) C. G. Claessens , D. González-Rodríguez , T. Torres , Chem. Rev. 2002 , 102 , 835 ; b) C. G. Claessens , D. González-Rodríguez , B. del Rey , T. Torres , G. Mark , H.-P. Schuchmann , C. von Sonntag , J. G. MacDonald , R. S. Nohr , Eur. J. Org. Chem. 2003 , 2547 . [ 18 ] B. W. D’Andrade , S. Datta , S. R. Forrest , P. Djurovich , E. Polikarpov , M. E. Thompson , Org. Electron. 2005 , 6 , 11 . [ 19 ] N. Sato , Y. Saito , H. Shinohara , Chem. Phys. 1992 , 162 , 433 . [ 20 ] S. W. Cho , L. F. J. Piper , A. DeMasi , A. R. H. Preston , K. E. Smith , K. V. Chauhan , P. Sullivan , R. A. Hatton , T. S. Jones , J. Phys. Chem. C 2010 , 114 , 1928 . [ 21 ] K. Schulze , C. Uhrich , R. Schuppel , K. Leo , M. Pfeiffer , E. Brier , E. Reinold , P. Bauerle , Adv. Mater. 2006 , 18 , 2872 . [ 22 ] H. Gommans , T. Aernouts , B. Verreet , P. Heremans , A. Medina , C. G. Claessens , T. Torres , Adv. Funct. Mater. 2009 , 19 , 3435 . [ 23 ] I. Hancox , K. V. Chauhan , P. Sullivan , R. A. Hatton , A. Moshar , C. P. A. Mulcahy , T. S. Jones , Energy Environ. Sci. 2010 , 3 , 107 . [ 24 ] D. Y. Kim , J. Subbiah , G. Sarasqueta , F. So , H. J. Ding Irfan , Y. L. Gao , Appl. Phys. Lett. 2009 , 95 , 093304 . [ 25 ] Z. A. Bao , A. J. Lovinger , J. Brown , J. Am. Chem. Soc. 1998 , 120 , 207 . [ 26 ] M. M. Ling , Z. N. Bao , P. Erk , Appl. Phys. Lett. 2006 , 89 , 163516 . [ 27 ] F. C. Krebs , K. Norrman , Progr. Photovoltaic Res. Appl. 2007 , 15 , 697 .
URI:	http://wrap.warwick.ac.uk/id/eprint/40004

Data sourced from Thomson Reuters' Web of Knowledge

Request changes to a record

Actions (login required)

View Item