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Unprecedented carbon–carbon bond formation induced by photoactivation of a platinum(iv)-diazido complex
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Ronconi, Luca and Sadler, P. J. (2008) Unprecedented carbon–carbon bond formation induced by photoactivation of a platinum(iv)-diazido complex. Chemical Communications (2). pp. 235-237. doi:10.1039/b714216a
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Official URL: http://dx.doi.org/10.1039/B714216A
Abstract
UVA-induced photodecomposition of a PtIV-diazido complex involves not only reduction to PtII and N2 release, but also O2 evolution and formation of nitrene intermediates, whose trapping with (CH3)2S gives rise to an unusual N,N′-bis(ethyl)sulfurousdiamide ligand in an apparently unprecedented process involving C–C bond formation.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Photochemistry, Chemical bonds, Carbon | ||||
| Journal or Publication Title: | Chemical Communications | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1359-7345 | ||||
| Official Date: | 14 January 2008 | ||||
| Dates: |
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| Number: | 2 | ||||
| Page Range: | pp. 235-237 | ||||
| DOI: | 10.1039/b714216a | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Seventh Framework Programme (European Commission) (FP7), Körber-Stiftung, Scottish Enterprise |
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