Ronconi, Luca and Sadler, P. J.. (2008) Unprecedented carbon–carbon bond formation induced by photoactivation of a platinum(iv)-diazido complex. Chemical Communications (2). pp. 235-237. ISSN 1359-7345

Full text not available from this repository.

Abstract

UVA-induced photodecomposition of a PtIV-diazido complex involves not only reduction to PtII and N2 release, but also O2 evolution and formation of nitrene intermediates, whose trapping with (CH3)2S gives rise to an unusual N,N′-bis(ethyl)sulfurousdiamide ligand in an apparently unprecedented process involving C–C bond formation.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Photochemistry, Chemical bonds, Carbon
Journal or Publication Title:	Chemical Communications
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Date:	14 January 2008
Number:	2
Page Range:	pp. 235-237
Identification Number:	10.1039/b714216a
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Seventh Framework Programme (European Commission) (FP7), Körber-Stiftung, Scottish Enterprise
References:	1 (a) P. Mu¨ller, B. Schro¨der, J. A. Parkinson, N. A. Kratochwil, R.A.Coxall, A. Parkin, S. Parsons and P. J. Sadler, Angew. Chem., Int. Ed., 2003, 42, 335–339; (b) P. J. Bednarski, F. S.Mackay andP. J.Sadler, Anti-Cancer Agents Med. Chem., 2007, 7, 75–93; (c) L. Ronconi and P. J. Sadler, Coord. Chem. Rev., 2007, 251, 1633–1648; (d) F. S.Mackay, J. A. Woods, H. Moseley, J. Ferguson, A. Dawson, S. Parsons and P. J. Sadler, Chem.–Eur. J., 2006, 12, 3155–3161. 2 J.Kasˇpa´rkova´, F. S. Mackay, V. Brabec and P. J. Sadler, JBIC, J. Biol. Inorg. Chem., 2003, 8, 741–745. 3 P. J. Bednarski, R. Gru¨nert, M. Zielzki, A. Wellner, F. S. Mackay and P. J. Sadler, Chem. Biol., 2006, 13, 61–67. 4 (a) A. Vogler, A. Kern, B. Fusseder and J. Hiittermann, Z. Naturforsch., B: Anorg. Chem., Org. Chem., 1978, 33, 1352–1356; (b) A. Vogler and J. Hlavatsch, Angew. Chem., Int. Ed. Engl., 1983, 22, 154–155. 5 J.E.Kent and E. L.Wagner, J. Chem. Phys., 1966, 44, 3530–3534. 6 V. R. Pai and M. Blais, J. Phys. Chem., 1968, 72, 774–778. 7 S. J. Berners-Price, L. Ronconi and P. J. Sadler, Prog. Nucl. Magn. Reson. Spectrosc., 2006, 49, 65–98. 8 (a) R. Kuroda, S. Neidle, I. M. Ismail and P. J. Sadler, Inorg. Chem., 1983, 22, 3620–3624; (b) C. F. J. Barnard, J. F. Vollano and P. A. Chaloner, Inorg. Chem., 1996, 35, 3280–3284; (c) J. Sykora and J. Sˇ ima, Coord. Chem. Rev., 1990, 107, 1–225. 9 M. J. P. Harger and S.Westlake, J. Chem. Soc., Perkin Trans. 1, 1984, 2351–2355. 10 (a) N. Sinyavsky and I. Korneva, Russ. Phys. J. (Transl. of Izv. Vyssh. Uchebn. Zaved., Fiz.), 2004, 47, 664–668; (b) N. Sinyavsky, I. Korneva and M. Mackowiak, J. Mol. Struct., 2003, 659, 43–51; (c) H. E. Gottlieb, V. Kotlyar and A. Nudelman, J. Org. Chem., 1997, 62, 7512–7515; (d) G. A. Olah, B. G. B. Gupta and S. C. Narang, J. Am. Chem. Soc., 1979, 101, 5317–5322; (e)M. R. Detty, J. Org. Chem., 1979, 44, 4528–4531. 11 (a) W. Ando, N. Ogino and T. Migita, Bull. Chem. Soc. Jpn., 1971, 44, 2278–2278; (b) W. Ando, Acc. Chem. Res., 1977, 10, 179–185. 12 (a) I. Barnes, J. Hjorth and N. Mihalopoulos, Chem. Rev., 2006, 106, 940–975; (b) Y. G. Adewuyi and G. R. Carmichael, Environ. Sci. Technol., 1986, 20, 1017–1022; (c) L. Zhu, J. M. Nicovich and P. H. Wine, Aquat. Sci., 2003, 65, 425–435. 13 (a) G.W.Watt, P. W. Alexander and B. S. Manhas, J. Am. Chem. Soc., 1967, 89, 6483–6487; (b) G. W. Watt and P. W. Alexander, Inorg. Chem., 1968, 7, 537–542.
URI:	http://wrap.warwick.ac.uk/id/eprint/40242

Request changes to a record

Actions (login required)

View Item