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Unprecedented carbon–carbon bond formation induced by photoactivation of a platinum(iv)-diazido complex
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Ronconi, Luca and Sadler, P. J. (2008) Unprecedented carbon–carbon bond formation induced by photoactivation of a platinum(iv)-diazido complex. Chemical Communications (2). pp. 235-237. doi:10.1039/b714216a ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/B714216A
Abstract
UVA-induced photodecomposition of a PtIV-diazido complex involves not only reduction to PtII and N2 release, but also O2 evolution and formation of nitrene intermediates, whose trapping with (CH3)2S gives rise to an unusual N,N′-bis(ethyl)sulfurousdiamide ligand in an apparently unprecedented process involving C–C bond formation.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Photochemistry, Chemical bonds, Carbon | ||||
Journal or Publication Title: | Chemical Communications | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1359-7345 | ||||
Official Date: | 14 January 2008 | ||||
Dates: |
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Number: | 2 | ||||
Page Range: | pp. 235-237 | ||||
DOI: | 10.1039/b714216a | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Funder: | Seventh Framework Programme (European Commission) (FP7), Körber-Stiftung, Scottish Enterprise |
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