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Unprecedented carbon–carbon bond formation induced by photoactivation of a platinum(iv)-diazido complex

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Ronconi, Luca and Sadler, P. J.. (2008) Unprecedented carbon–carbon bond formation induced by photoactivation of a platinum(iv)-diazido complex. Chemical Communications (2). pp. 235-237. ISSN 1359-7345

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Abstract

UVA-induced photodecomposition of a PtIV-diazido complex involves not only reduction to PtII and N2 release, but also O2 evolution and formation of nitrene intermediates, whose trapping with (CH3)2S gives rise to an unusual N,N′-bis(ethyl)sulfurousdiamide ligand in an apparently unprecedented process involving C–C bond formation.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Photochemistry, Chemical bonds, Carbon
Journal or Publication Title: Chemical Communications
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Official Date: 14 January 2008
Number: 2
Page Range: pp. 235-237
Identification Number: 10.1039/b714216a
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Seventh Framework Programme (European Commission) (FP7), Körber-Stiftung, Scottish Enterprise
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URI: http://wrap.warwick.ac.uk/id/eprint/40242

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