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RAFT polymerization meets coordination chemistry : synthesis of a polymer-based iridium(III) emitter
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Ulbricht, Christoph, Becer, C. Remzi, Winter, Andreas and Schubert, Ulrich S. (2010) RAFT polymerization meets coordination chemistry : synthesis of a polymer-based iridium(III) emitter. Macromolecular Rapid Communications, Vol.31 (No.9-10). pp. 827-833. doi:10.1002/marc.200900787 ISSN 1022-1336.
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Official URL: http://dx.doi.org/10.1002/marc.200900787
Abstract
A synthetic approach toward the synthesis of well-defined copolymers with attached phosphorescent iridium(III) emitters is presented. A reactive ยต-hydroxy-bridged precursor complex has been utilized to coordinate suitable ligand sites of a methacrylate-based copolymer. The starting copolymer has been synthesized via the reversible addition fragmentation chain transfer (RAFT) polymerization technique. Using a reactive complex species, the coordination reaction at the copolymer could be performed under very mild conditions in the absence of any supporting additives.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Polymerization, Coordination compounds, Copolymers | ||||
Journal or Publication Title: | Macromolecular Rapid Communications | ||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
ISSN: | 1022-1336 | ||||
Official Date: | 2010 | ||||
Dates: |
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Volume: | Vol.31 | ||||
Number: | No.9-10 | ||||
Page Range: | pp. 827-833 | ||||
DOI: | 10.1002/marc.200900787 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Funder: | Dutch Polymer Institute (DPI), Nederlandse Organisatie voor Wetenschappelijk Onderzoek [Nederlands Organization for Scientific Research] (NWO), Fonds der Chemischen Industrie (Germany) |
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