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Tailor made side-chain functionalized macromolecules by combination of controlled radical polymerization and click chemistry
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Krieg, Andreas, Becer, C. Remzi, Hoogenboom, Richard and Schubert, Ulrich S. (2009) Tailor made side-chain functionalized macromolecules by combination of controlled radical polymerization and click chemistry. Macromolecular Symposia, Vol.275-276 (No.1). pp. 73-81. doi:10.1002/masy.200950109 ISSN 1022-1360.
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Official URL: http://dx.doi.org/10.1002/masy.200950109
Abstract
Reversible addition-fragmentation chain transfer polymerization of trimethylsilyl-propargyl methacrylate (TMSPMA) was performed to obtain alkyne containing polymers with narrow molecular weight distributions (PDI < 1.3). Homopolymers of TMSPMA as well as random and block copolymers with methyl methacrylate were synthesized and subsequently deprotected. The obtained acetylene-functionalized polymers were further functionalized using the copper(I) catalyzed alkyne-azide cycloaddition reaction to obtain well-defined glycopolymers, grafted copolymers and anthracene-containing polymers (PDI = 1.08–1.28) that were characterized with GPC, MALDI-TOF mass spectrometry and 1H-NMR-spectroscopy.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Polymerization, Macromolecules, Graft copolymers | ||||
Journal or Publication Title: | Macromolecular Symposia | ||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
ISSN: | 1022-1360 | ||||
Official Date: | 2009 | ||||
Dates: |
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Volume: | Vol.275-276 | ||||
Number: | No.1 | ||||
Page Range: | pp. 73-81 | ||||
DOI: | 10.1002/masy.200950109 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Funder: | Dutch Polymer Institute (DPI), Thuringia (Germany). Ministerium für Bildung, Wissenschaft und Kultur, Fonds der Chemischen Industrie (Germany) | ||||
Grant number: | B515-07008 (TMBWK) |
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