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In vivo trapping of polyketide intermediates from an assembly line synthase using malonyl carba(dethia)-N-acetyl cysteamines

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Tosin, Manuela, Demydchuk, Yuliya, Parascandolo, James S., Blasco Per, Covadonga, Leeper, F. J. (Finian J.) and Leadlay, P. F. (2011) In vivo trapping of polyketide intermediates from an assembly line synthase using malonyl carba(dethia)-N-acetyl cysteamines. Chemical Communications, Vol.47 (No.12). pp. 3460-3462. doi:10.1039/c0cc05077f

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Official URL: http://dx.doi.org/10.1039/C0CC05077F

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Abstract

Early-stage intermediates in the biosynthesis of erythromycin A by Saccharopolyspora erythraea were intercepted by malonyl carba(dethia)-N-acetyl cysteamines, generated in vivo from the hydrolysis of the corresponding methyl esters.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Q Science > QP Physiology
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Polyketides -- Therapeutic use, Biosynthesis, Enzymes, Hydrolysis
Journal or Publication Title: Chemical Communications
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Official Date: 2011
Dates:
DateEvent
2011Published
Volume: Vol.47
Number: No.12
Page Range: pp. 3460-3462
DOI: 10.1039/c0cc05077f
Status: Peer Reviewed
Publication Status: Published
Funder: University of Cambridge Herchel Smith Fund

Data sourced from Thomson Reuters' Web of Knowledge

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