Parekh, Vimal, Ramsden, James A. and Wills, Martin (2012) Ether-tethered Ru(ii)/TsDPEN complexes : synthesis and applications to asymmetric transfer hydrogenation. Catalysis Science & Technology, Vol.2 (No.2). pp. 406-414. doi:10.1039/c1cy00364j ISSN 2044-4753.

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Abstract

A new type of Ru(II)/TsDPEN catalyst containing an ether-based linking tether has been prepared and shown to exhibit excellent activity in asymmetric transfer hydrogenation reactions of ketones. Related complexes containing a hydroxyl-terminated alkyl chain have also been prepared and tested as asymmetric catalysts. In some cases the activity of the new catalyst type complements that of the closely related alkyl-chain tethered complexes.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science, Engineering and Medicine > Science > Chemistry
Library of Congress Subject Headings (LCSH):	Ruthenium compounds, Metal catalysts, Hydrogenation, Ketones
Journal or Publication Title:	Catalysis Science & Technology
Publisher:	Royal Society of Chemistry
ISSN:	2044-4753
Official Date:	2012
Dates:	Date Event 2012 Published
Volume:	Vol.2
Number:	No.2
Page Range:	pp. 406-414
DOI:	10.1039/c1cy00364j
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Date of first compliant deposit:	18 December 2015
Date of first compliant Open Access:	18 December 2015
Funder:	Engineering and Physical Sciences Research Council (EPSRC), Dr. Reddy's Laboratories

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