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Developing asymmetric iron and ruthenium-based cyclone complexes : complex factors influence the asymmetric induction in the transfer hydrogenation of ketones
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Hopewell, Jonathan P., Martins, José E. D., Johnson, Tarn C., Godfrey, Jamie and Wills, Martin (2012) Developing asymmetric iron and ruthenium-based cyclone complexes : complex factors influence the asymmetric induction in the transfer hydrogenation of ketones. Organic & Biomolecular Chemistry, Vol.10 (No.1). pp. 134-145. doi:10.1039/c1ob06010d ISSN 1477-0520.
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WRAP_Wills__OB-ART-06-2011-006010_resubmission_aug_2011_(2).pdf - Accepted Version - Requires a PDF viewer. Download (439Kb) |
Official URL: http://dx.doi.org/10.1039/C1OB06010D
Abstract
The preparation of a range of asymmetric iron and ruthenium-cyclone complexes, and their application to the asymmetric reduction of a ketone, are described. The enantioselectivity of ketone reduction is influenced by a single chiral centre in the catalyst, as well as by the planar chirality in the catalyst. This represents the first example of asymmetric ketone reduction using an iron cyclone catalyst.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Asymmetric synthesis, Ketones, Iron, Ruthenium | ||||
Journal or Publication Title: | Organic & Biomolecular Chemistry | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1477-0520 | ||||
Official Date: | 2012 | ||||
Dates: |
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Volume: | Vol.10 | ||||
Number: | No.1 | ||||
Page Range: | pp. 134-145 | ||||
DOI: | 10.1039/c1ob06010d | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Date of first compliant deposit: | 18 December 2015 | ||||
Date of first compliant Open Access: | 18 December 2015 | ||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC), University of Warwick | ||||
Grant number: | EP/F019424 (EPSRC), EP/G01244X/1 (EPSRC) |
Data sourced from Thomson Reuters' Web of Knowledge
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