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Application of proline-functionalised 1,2-diphenylethane-1,2-diamine (DPEN) in asymmetric transfer hydrogenation of ketones
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Manville, Charles, Docherty, Gordon, Padda, Ranbir and Wills, Martin. (2011) Application of proline-functionalised 1,2-diphenylethane-1,2-diamine (DPEN) in asymmetric transfer hydrogenation of ketones. European Journal of Organic Chemistry, Vol.2011 (No.34). pp. 6893-6901. ISSN 1434-193X
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Official URL: http://dx.doi.org/10.1002/ejoc.201101164
Abstract
A series of enantiomerically pure ligands containing a combination of proline and DPEN groups have been prepared and employed in the asymmetric transfer hydrogenation of ketones. In the case of cyclic ketones, alcohols with ee values of up to 98 % were obtained.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Science > Chemistry |
| Library of Congress Subject Headings (LCSH): | Ketones, Hydrogenation, Ruthenium, Iridium, Peptides |
| Journal or Publication Title: | European Journal of Organic Chemistry |
| Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA |
| ISSN: | 1434-193X |
| Date: | 2011 |
| Volume: | Vol.2011 |
| Number: | No.34 |
| Page Range: | pp. 6893-6901 |
| Identification Number: | 10.1002/ejoc.201101164 |
| Status: | Peer Reviewed |
| Publication Status: | Published |
| Funder: | Engineering and Physical Sciences Research Council (EPSRC), Rhodia Consumer Specialties Ltd. |
| URI: | http://wrap.warwick.ac.uk/id/eprint/40373 |
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