Soni, Rina, Cheung, Fung Kei, Clarkson, Guy C., Martins, Jose E. D., Graham, Mark A. and Wills, Martin. (2011) The importance of the N–H bond in Ru/TsDPEN complexes for asymmetric transfer hydrogenation of ketones and imines. Organic & Biomolecular Chemistry, Vol.9 (No.9). pp. 3290-3294. ISSN 1477-0520

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Abstract

Ru(II) complexes of TsDPEN containing two alkyl groups on the non-tosylated nitrogen atom are poor catalysts for asymmetric transfer hydrogenation of ketones and imines; this observation provides direct evidence for the importance of the N–H interaction in the transition state for ketone reduction.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Hydrogenation, Ketones, Imines, Ruthenium
Journal or Publication Title:	Organic & Biomolecular Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1477-0520
Date:	2011
Volume:	Vol.9
Number:	No.9
Page Range:	pp. 3290-3294
Identification Number:	10.1039/c1ob05208j
Status:	Peer Reviewed
Publication Status:	Published
Funder:	University of Warwick , Engineering and Physical Sciences Research Council (EPSRC) , AstraZeneca (Firm)
Grant number:	EP/F019424 (EPSRC)
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URI:	http://wrap.warwick.ac.uk/id/eprint/40377

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