The Library
Gold-catalysed cyclic ether formation from diols
Tools
Jiang, Xiaoli, London, Emma K., Morris, David J., Clarkson, Guy J. and Wills, Martin (2010) Gold-catalysed cyclic ether formation from diols. Tetrahedron, Vol.66 (No.52). pp. 9828-9834. doi:10.1016/j.tet.2010.10.068 ISSN 0040-4020 .
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Official URL: http://dx.doi.org/10.1016/j.tet.2010.10.068
Abstract
Gold(I) and (III) salts have been found to be highly effective at the catalysis of ether formation from alcohols. Intramolecular ether formation of a 1,5-diol was also achieved, with a stereoselectivity that indicates that an SN1 mechanism predominates. In an attempt to form a seven-membered ring, a stable 14-membered dimer product was also formed. Attempts to control the diastereoselectivity of the reaction using a chiral anionic counterion did not give products with a high de.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Gold, Catalysis, Ring formation (Chemistry), Glycols, Ether | ||||
Journal or Publication Title: | Tetrahedron | ||||
Publisher: | Pergamon | ||||
ISSN: | 0040-4020 | ||||
Official Date: | 2010 | ||||
Dates: |
|
||||
Volume: | Vol.66 | ||||
Number: | No.52 | ||||
Page Range: | pp. 9828-9834 | ||||
DOI: | 10.1016/j.tet.2010.10.068 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC), University of Warwick | ||||
Grant number: | EP/F061420/1 (EPSRC) |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |