The Library

Chiral semiconductor phases : the optically pure D3[MIII(S,S-EDDS)]2(D = TTF, TSF) family

Tools

Chmel, Nikola Paul, Clarkson, Guy J., Troisi, Alessandro, Turner, S. S. and Scott, Peter. (2011) Chiral semiconductor phases : the optically pure D3[MIII(S,S-EDDS)]2(D = TTF, TSF) family. Inorganic Chemistry, Vol.50 (No.9). pp. 4039-4046. ISSN 0020-1669

Full text not available from this repository.

Official URL: http://dx.doi.org/10.1021/ic102522k

Abstract

A new family of optically pure tetrathiafulvalenium and tetraselenafulvalenium salts, D3[MIII(S,S-EDDS)]2·nH2O (where D = TTF, TSF; M = Co, Fe, Cr; EDDS = ethylenediaminedisuccinato), were synthesized electrochemically. These phases are semiconductors with conductivities between 6.9 × 10−6 and 1.3 × 10−5 S·cm−1 (Eaca. 0.3 eV) for TTF and 2.8 × 10−4 to 2.8 × 10−5 S·cm−1 (Eaca. 0.1 eV) for TSF compounds. While some crystals suffer from twinning, other well resolved structures consist of TTF/TSF stacks which, under the influence of the chiral anion, exhibit a periodic undulation described by an elliptical helix. The crystallographic data, along with computational work, indicate charge localization in the semiconducting motifs.

Item Type:

Journal Article

Subjects:

Q Science > QC Physics
Q Science > QD Chemistry
Q Science > QP Physiology

Divisions:

Faculty of Science > Chemistry

Library of Congress Subject Headings (LCSH):

Semiconductors, Chirality, Charge transfer, Tetrathiafulvalene

Journal or Publication Title:

Inorganic Chemistry

Publisher:

American Chemical Society

ISSN:

0020-1669

Official Date:

2011

Dates:

Date	Event
2011	Published

Volume:

Vol.50

Number:

No.9

Page Range:

pp. 4039-4046

Identification Number:

10.1021/ic102522k

Status:

Peer Reviewed

Publication Status:

Published

Funder:

Engineering and Physical Sciences Research Council (EPSRC)

References:

(1) Rikken, G. L. J. A.; Folling, J.; Wyder, P. Phys. Rev. Lett. 2001, 87
(23), 236602.
(2) Krstic, V.; Rikken, G. L. J. A. Chem. Phys. Lett. 2002, 364 (1-2),
51–56.
(3) Coronado, E.; Galan-Mascaros, J. R. J. Mater. Chem. 2005, 15
(1), 66–74.
(4) Krstic, V.; Roth, S.; Burghard, M.; Kern, K.; Rikken, G. L. J. A.
J. Chem. Phys. 2002, 117 (24), 11315–11319.
(5) Gomar-Nadal, E.; Veciana, J.; Rovira, C.; Amabilino, D. Adv.
Mater. 2005, 17 (17), 2095–2098.
(6) Yamamoto, T.; Fukushima, T.; Kosaka, A.; Jin, W.; Yamamoto,
Y.; Ishii, N.; Aida, T. Angew. Chem., Int. Ed. 2008, 47 (9), 1672–1675.
(7) Martin, L.; Day, P.; Horton, P.; Nakatsuji, S.; Yamada, J.; Akutsu,
H. J. Mater. Chem. 2010, 20 (14), 2738–2742.
(8) Brezgunova, M.; Shin, K.-S.; Auban-Senzier, P.; Jeannin, O.;
Fourmigue, M. Chem. Commun. 2010, 46 (22), 3926–3928.
(9) Coronado, E.; Curreli, S.; Gim�enez-Saiz, C.; G�omez-García,
C. J.; Roth, J. Synth. Met. 2005, 154 (1�3), 241–244.
(10) Gal�an-Mascar�os, J. R.; Coronado, E.; Goddard, P. A.; Singleton,
J.; Coldea, A. I.; Wallis, J. D.; Coles, S. J.; Alberola, A. J. Am. Chem. Soc.
2010, 132 (27), 9271–9273.
(11) Inabe, T. J. Mater. Chem. 2005, 15 (13), 1317–1328.
(12) Avarvari, N.; Wallis, J. D. J. Mater. Chem. 2009, 19 (24),
4061–4076.
(13) Wallis, J. D.; Karrer, A.; Dunitz, J. D. Helv. Chim. Acta 1986, 69
(1), 69–70.
(14) Zambounis, J. S.; Mayer, C. W.; Hauenstein, K.; Hilti, B.;
Hofherr, W.; Pfeiffer, J.; Buerkle, M.; Rihs, G. Mater. Res. Soc. Symp. Proc.
1992, 247, 509–13.
(15) Coronado, E.; Galan-Mascaros, J. R.; Gomez-Garcia, C. J.;
Murcia-Martinez, A.; Canadell, E. Inorg. Chem. 2004, 43, 8072–8077.
(16) Chmel, N. P.; Allan, L. E.; Becker, J. M.; Clarkson, G. J.; Turner,
S. S.; Scott, P. Dalton Trans. 2011, 40, 1722–1731.
(17) Neal, J. A.; Rose, N. J. Inorg. Chem. 1968, 7 (11), 2405–2412.
(18) Chmel, N. P.; Howson, S. E.; Allan, L. E. N.; Barker, J.;
Clarkson, G. J.; Turner, S. S.; Scott, P. Dalton Trans. 2010, 39 (11),
2919–2927.
(19) Melby, L. R.; Hartzler, H. D.; Sheppard, W. A. J. Org. Chem.
1974, 39 (16), 2456–2458.
(20) Takimiya, K.; Jeon, H. J.; Otsubo, T. Synthesis 2005, 2005 (16),
2810–2813.
(21) Clemente, D. A.; Marzotto, A. J. Mater. Chem. 1996, 6 (6),
941–946.
(22) Spek, A. J. Appl. Crystallogr. 2003, 36 (1), 7–13.
(23) Sheldrick, G. M. Acta Crystallogr., Sect. A 2008, 64, 112–122.
(24) Makovicky, E.; Hyde, B. In Inorganic Chemistry; Springer:
Berlin, 1981; Vol. 46, pp 101-170.
(25) Coronado, E.; Galan-Mascaros, J. R.; Gomez-García, C. J.;
Martínez-Ferrero, E.; van Smaalen, S. Inorg. Chem. 2004, 43 (16),
4808–4810.
(26) Matsuzaki, S.; Koga, N.; Moriyama, I.; Toyoda, K. Bull. Chem.
Soc. Jpn. 1983, 56 (7), 2090–2092.
(27) Bacon, A. D.; Zerner, M. C. Theor. Chim. Acta 1979, 53 (1),
21–54.
(28) Becke, A. D. J. Chem. Phys. 1993, 98 (7), 5648–5652.
(29) Lee, C.; Yang, W.; Parr, R. G. Phys. Rev. B 1988, 37 (2), 785.
(30) Sheldrick, G. M. Acta Crystallogr., Sect. A 1990, 46, 467–473.
(31) Farrugia, L. J. Appl. Crystallogr. 1999, 32 (4), 837–838.