Chen, Rong, Pearce, Daniel J. G., Fortuna, S. (Sara), Cheung, David L. and Bon, Stefan Antonius Franciscus. (2011) Polymer vesicles with a colloidal armor of nanoparticles. Journal of the American Chemical Society, Vol.133 (No.7). pp. 2151-2153. ISSN 0002-7863

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Abstract

The fabrication of polymer vesicles with a colloidal armor made from a variety of nanoparticles is demonstrated. In addition, it is shown that the armored supracolloidal structure can be postmodified through film-formation of soft polymer latex particles on the surface of the polymersome, hereby effectively wrapping the polymersome in a plastic bag, as well as through formation of a hydrogel by disintegrating an assembled polymer latex made from poly(ethyl acrylate-co-methacrylic acid) upon increasing the pH. Furthermore, ordering and packing patterns are briefly addressed with the aid of Monte Carlo simulations, including patterns observed when polymersomes are exposed to a binary mixture of colloids of different size.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry T Technology > TA Engineering (General). Civil engineering (General)
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Stabilizing agents, Copolymers, Coated vesicles, Nanoparticles
Journal or Publication Title:	Journal of the American Chemical Society
Publisher:	American Chemical Society
ISSN:	0002-7863
Date:	23 February 2011
Volume:	Vol.133
Number:	No.7
Page Range:	pp. 2151-2153
Identification Number:	10.1021/ja110359f
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
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URI:	http://wrap.warwick.ac.uk/id/eprint/40398

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