Skip to content Skip to navigation
University of Warwick
  • Study
  • |
  • Research
  • |
  • Business
  • |
  • Alumni
  • |
  • News
  • |
  • About

University of Warwick
Publications service & WRAP

Highlight your research

  • WRAP
    • Home
    • Search WRAP
    • Browse by Warwick Author
    • Browse WRAP by Year
    • Browse WRAP by Subject
    • Browse WRAP by Department
    • Browse WRAP by Funder
    • Browse Theses by Department
  • Publications Service
    • Home
    • Search Publications Service
    • Browse by Warwick Author
    • Browse Publications service by Year
    • Browse Publications service by Subject
    • Browse Publications service by Department
    • Browse Publications service by Funder
  • Help & Advice
University of Warwick

The Library

  • Login
  • Admin

Exploring (Ph2PCH2CH2)2E ligand space (E = O, S, PPh) in RhI alkene complexes as potential hydroacylation catalysts

Tools
- Tools
+ Tools

Pike, Sebastian D., Pawley, R, Chaplin, Adrian B., Thompson, Amber L., Hooper, Joel A., Willis, Michael C. and Weller, Andrew S. (2011) Exploring (Ph2PCH2CH2)2E ligand space (E = O, S, PPh) in RhI alkene complexes as potential hydroacylation catalysts. European Journal of Inorganic Chemistry, Vol.2011 (No.36). pp. 5558-5565. doi:10.1002/ejic.201100958

Research output not available from this repository, contact author.
Official URL: http://dx.doi.org/10.1002/ejic.201100958

Request Changes to record.

Abstract

The ligands (Ph2PCH2CH2)2E (E = O, S, PPh) have been used to form a variety of RhI cations [Rh{(Ph2PCH2CH2)2E}(alkene)]+ (alkene = methyl acrylate, trimethylvinylsilane). Variable-temperature NMR spectroscopy shows that the methyl acrylate ligands undergo a fluxional process on the metal, via a κ1-carbonyl intermediate, while the trimethylvinylsilane complexes cannot access this intermediate and do not undergo the same process. Their reactivity in hydroacylation reactions with 1-pentanal have been investigated, and these studies further suggest the important role that a chelating substituent next to the aldehyde might play in productive hydroacylation.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Rhodium, Nuclear magnetic resonance spectroscopy, Alkenes, Catalysts, Ligands
Journal or Publication Title: European Journal of Inorganic Chemistry
Publisher: Wiley-VCH Verlag GMBH
ISSN: 1434-1948
Official Date: December 2011
Dates:
DateEvent
December 2011Published
Volume: Vol.2011
Number: No.36
Page Range: pp. 5558-5565
DOI: 10.1002/ejic.201100958
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Engineering and Physical Sciences Research Council (EPSRC), University of Oxford

Request changes or add full text files to a record

Repository staff actions (login required)

View Item View Item
twitter

Email us: wrap@warwick.ac.uk
Contact Details
About Us