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A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H : an intermediate in the dehydrocoupling of H3B·NMe2H

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Chaplin, Adrian B. and Weller, Andrew S. (2011) A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H : an intermediate in the dehydrocoupling of H3B·NMe2H. Acta Crystallographica. Section C: Crystal Structure Communications, Vol.67 (No.11). m355-m358. doi:10.1107/S0108270111043447

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Official URL: http://dx.doi.org/10.1107/S0108270111043447

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Abstract

The solid-state structure of the rhodium complex (dimethylamine-dimethylaminoborane-borane-kappa(2)H,H')dihydridobis-(triisopropylphosphane-kappa P)rhodium(III) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate, [RhH(2)(C(4)H(18)B(2)N(2))(C(9)H(21)P)(2)](C(32)H(12)BF(24)), is reported. The complex contains the linear diborazine H(3)B center dot NMe(2)BH(2)center dot NMe(2)H, a kinetically important intermediate in the transition-metal-mediated dehydrocoupling of H(3)B center dot NMe(2)H, ultimately affording the dimeric amino-borane [H(2)BNMe(2)](2). The structure of the title complex contains a distorted octahedral Rh(III) centre, with mutually trans phosphane ligands and cis hydride ligands. The diborazine is bound through two Rh-H-B sigma-bonds and exhibits a gauche conformation with respect to the B-N-B-N backbone.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Rhodium, Transition metal complexes
Journal or Publication Title: Acta Crystallographica. Section C: Crystal Structure Communications
Publisher: Wiley-Blackwell Publishing, Inc.
ISSN: 0108-2701
Official Date: November 2011
Dates:
DateEvent
November 2011Published
Volume: Vol.67
Number: No.11
Page Range: m355-m358
DOI: 10.1107/S0108270111043447
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Engineering and Physical Sciences Research Council (EPSRC), University of Oxford

Data sourced from Thomson Reuters' Web of Knowledge

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