Chaplin, Adrian B. and Weller, Andrew S.. (2011) [Rh{NC5H3-2,6-(CH2PtBu2)2}(PCy3)][BArF4] : a latent low-coordinate rhodium(I) PNP pincer compound. Organometallics, Vol.30 (No.16). pp. 4466-4469. ISSN 0276-7333

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Abstract

An expedient new route to the cationic [(PNPtBu)Rh(L)]+ metal fragments (PNPtBu = κ3-NC5H3-2,6-(CH2P tBu2)2; L = CO, acetone, ethene, MeCN, N2) by the synthesis of, then substitution of PCy3 in, [(PNPtBu)Rh(PCy3)][BArF4] is reported. This synthetic route also allows for the synthesis of the new dihydrogen complex [(PNPtBu)Rh(H2)][BArF4]. [(PNPR)Rh(PCy3)][BArF4] (R= Ph, Cy, Mes) are also reported, in which the PCy3 ligand is more tightly bound to the metal center.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Rhodium, Organometallic compounds, Biosynthesis, Ligands
Journal or Publication Title:	Organometallics
Publisher:	American Chemical Society
ISSN:	0276-7333
Date:	22 August 2011
Volume:	Vol.30
Number:	No.16
Page Range:	pp. 4466-4469
Identification Number:	10.1021/om2004964
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Engineering and Physical Sciences Research Council (EPSRC)
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URI:	http://wrap.warwick.ac.uk/id/eprint/40491

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