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Catching the first oligomerization event in the catalytic formation of polyaminoboranes : H3B·NMeHBH2·NMeH2 bound to iridium

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Johnson, Heather C., Robertson, Alasdair P. M., Chaplin, Adrian B., Sewell, Laura J., Thompson, Amber L., Haddow, Mairi F., Manners, Ian and Weller, Andrew S. (2011) Catching the first oligomerization event in the catalytic formation of polyaminoboranes : H3B·NMeHBH2·NMeH2 bound to iridium. Journal of the American Chemical Society, Vol.133 (No.29). pp. 11076-11079. doi:10.1021/ja2040738

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Official URL: http://dx.doi.org/10.1021/ja2040738

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Abstract

We report the first insertion step at a metal center for the catalytic dehydropolymerization of H(3)B center dot NMeH(2) to form the simplest oligomeric species, H(3)B center dot NMeHBH(2)center dot NMeH(2), by the addition of 1 equiv of H(3)B center dot NMeH(2) to [Ir(PCy(3))(2)(H)(2)(eta(2)-H(3)B center dot NMeH(2))] [BAr(4)(F)] to give [Ir(PCy(3))(2)(H)(2)(eta(2)-H(3)B center dot NMeHBH(2)center dot NMeH(2))] [BAr(4)(F)]. This reaction is also catalytic for the formation of the free linear diborazane, but this is best obtained by an alternative stoichiometric synthesis.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Oligomers, Iridium, Catalysis, Polymerization
Journal or Publication Title: Journal of the American Chemical Society
Publisher: American Chemical Society
ISSN: 0002-7863
Official Date: 27 July 2011
Dates:
DateEvent
27 July 2011Published
Volume: Vol.133
Number: No.29
Page Range: pp. 11076-11079
DOI: 10.1021/ja2040738
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: University of Oxford, Engineering and Physical Sciences Research Council (EPSRC)

Data sourced from Thomson Reuters' Web of Knowledge

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