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Hydroboration of an alkene by amine–boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation
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Sewell, Laura J., Chaplin, Adrian B. and Weller, Andrew S. (2011) Hydroboration of an alkene by amine–boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation. Dalton Transactions, Vol.40 (No.29). pp. 7499-7501. doi:10.1039/c1dt10819k ISSN 1477-9226.
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Official URL: http://dx.doi.org/10.1039/c1dt10819k
Abstract
The catalytic hydroboration of tert-butylethene using H(3)B center dot NMe(3) gives RH(2)B center dot NMe(3). With H(3)B center dot NMe(2)H tandem hydroboration under mild conditions/dehydrocoupling occurs that produces R(2)B=NMe(2) (R = H, CH(2)CH(2)(t)Bu).
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Hydroboration, Alkenes, Dehydrogenation, Catalysis | ||||
Journal or Publication Title: | Dalton Transactions | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1477-9226 | ||||
Official Date: | 7 August 2011 | ||||
Dates: |
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Volume: | Vol.40 | ||||
Number: | No.29 | ||||
Page Range: | pp. 7499-7501 | ||||
DOI: | 10.1039/c1dt10819k | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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