Sewell, Laura J., Chaplin, Adrian B. and Weller, Andrew S.. (2011) Hydroboration of an alkene by amine–boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation. Dalton Transactions, Vol.40 (No.29). pp. 7499-7501. ISSN 1477-9226

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Abstract

The catalytic hydroboration of tert-butylethene using H(3)B center dot NMe(3) gives RH(2)B center dot NMe(3). With H(3)B center dot NMe(2)H tandem hydroboration under mild conditions/dehydrocoupling occurs that produces R(2)B=NMe(2) (R = H, CH(2)CH(2)(t)Bu).

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Hydroboration, Alkenes, Dehydrogenation, Catalysis
Journal or Publication Title:	Dalton Transactions
Publisher:	Royal Society of Chemistry
ISSN:	1477-9226
Date:	7 August 2011
Volume:	Vol.40
Number:	No.29
Page Range:	pp. 7499-7501
Identification Number:	10.1039/c1dt10819k
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
References:	1 C. A. Jaska, K. Temple, A. J. Lough and I. Manners, J. Am. Chem. Soc., 2003, 125, 9424–9434. 2 M. E. Sloan, T. J. Clark and I. Manners, Inorg. Chem., 2009, 48, 2429– 2435. 3 A. Staubitz, A. P. M. Robertson, M. E. Sloan and I. Manners, Chem. Rev., 2010, 110, 4023–4078. 4 A. B. Chaplin and A. S. Weller, Inorg. Chem., 2010, 49, 1111–1121. 5 T.M. Douglas, A. B. Chaplin, A. S.Weller, X. Yang andM. B. Hall, J. Am. Chem. Soc., 2009, 131, 15440–15456. 6 R. Dallanegra, A. P. M. Robertson, A. B. Chaplin, I. Manners and A. S. Weller, Chem. Commun., 2011, 47, 3763–3765. 7 A. B. Chaplin and A. S. Weller, Angew. Chem. Int. Ed., 2010, 49, 581– 584. 8 K. Burgess, W. A. van der Donk, S. A. Westcott, T. B. Marder, R. T. Baker and J. C. Calabrese, J. Am. Chem. Soc., 1992, 114, 9350–9359;D. A. Evans, G. C. Fu and B. A. Anderson, J. Am. Chem. Soc., 1992, 114, 6679–6685; J. M. Brown and G. C. Lloyd-Jones, J. Am. Chem. Soc., 1994, 116, 866–878. 9 D. Mannig and H. Noth, Angew. Chem., Int. Ed. Engl., 1985, 24, 878– 879. 10 C. J. Chapman and C. G. Frost, Synthesis, 2007, 2007, 1–21; D. E. Fogg and E. N. dos Santos, Coord. Chem. Rev., 2004, 248, 2365– 2379. 11 L. J. Sewell, A. B. Chaplin, J. A. B. Abdalla and A. S. Weller, Dalton Trans., 2010, 39, 7437–7439. 12 G. J. Kubas, Metal Dihydrogen and o-Bond Complexes, Kluwer Academic/Plenum Publishers, New York, 2001. 13 S. A.Westcott, T. B. Marder, R. T. Baker, R. L.Harlow, J. C. Calabrese, K. C. Lam and Z. Y. Lin, Polyhedron, 2004, 23, 2665–2677. 14 N. Merle,G.Koicok-Kohn, M. F. Mahon, C.G. Frost,G.D. Ruggerio, A. S. Weller and M. C. Willis, Dalton Trans., 2004, 3883–3892; G. Alcaraz and S. Sabo-Etienne, Coord. Chem.Rev., 2008, 252, 2395–2409. 15 Y. Kawano, K. Yamaguchi, S. Y.Miyake, T. Kakizawa andM. Shimoi, Chem.–Eur. J., 2007, 13, 6920–6931. 16 W. H. Bernskoetter, C. K. Schauer, K. I. Goldberg and M. Brookhart, Science, 2009, 326, 553–556. 17 T. C. Morrill, C. A. D’Souza, L. Yang and A. J. Sampognaro, J. Org. Chem., 2002, 67, 2481–2484. 18 J. D. Hewes, C. W. Kreimendahl, T. B. Marder and M. F. Hawthorne, J. Am. Chem. Soc., 1984, 106, 5757–5759; E. Molinos, S. K. Brayshaw, G. Kociok-K¨ohn and A. S. Weller, Organometallics, 2007, 26, 2370– 2382. 19 C. Y. Tang, A. L. Thompson and S. Aldridge, J. Am. Chem. Soc., 2010, 132, 10578–10591. 20 M. E. Sloan, A. Staubitz, K. Lee and I. Manners, Eur. J. Org. Chem., 2011, 2011, 672–675; Y. Jiang, J. Hess, T. Fox and H. Berke, J. Am. Chem. Soc., 2010, 132, 18233–18247. 21 H. Feulner, N. Metzler and H. N¨ oth, J. Organomet. Chem., 1995, 489, 51–62; L. Euzenat,D. Horhant,Y.Ribourdouille,C. Duriez,G. Alcaraz and M. Vaultier, Chem. Commun., 2003, 2280–2281; T. Miyazaki, Y. Tanabe, M. Yuki, Y. Miyake and Y. Nishibayashi, Organometallics, 2011, 30, 2394–2404.
URI:	http://wrap.warwick.ac.uk/id/eprint/40497

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