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{Rh(PiBu3)2}+ fragments ligated to arenes : from benzene to polyaromatic hydrocarbons, part I - an experimental approach
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Woolf, Anthony, Chaplin, Adrian B., McGrady, John E., Alibadi, Muhsen A. M., Rees, Nicholas H., Draper, Sylvia, Murphy, F. (Frances) and Weller, Andrew S. (2011) {Rh(PiBu3)2}+ fragments ligated to arenes : from benzene to polyaromatic hydrocarbons, part I - an experimental approach. European Journal of Inorganic Chemistry, Vol.2011 (No.10). pp. 1614-1625. doi:10.1002/ejic.201001263 ISSN 1434-1948.
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Official URL: http://dx.doi.org/10.1002/ejic.201001263
Abstract
We report the synthesis, structural characterisation and solution-phase dynamics of a series of polyaromatic hydrocarbon complexes of the 12-electron {Rh(PiBu(3))(2)}(+) fragment. Crystal structures of this fragment with benzene, naphthalene, anthracene, pyrene, triphenylene and coronene are described, alongside their solution NMR spectroscopic data. The ligands map out a systematic increase in size of the aromatic subunit, and represent an approach to the limiting case of coordination to a graphene surface. The solid-state and solution structures of a {Rh(COD)}(+) fragment coordinated to a hexa-peri-hexabenzocoronene are also reported.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Rhodium, Aromatic compounds, Ligands, Hydrocarbons, Polycyclic aromatic hydrocarbons | ||||
Journal or Publication Title: | European Journal of Inorganic Chemistry | ||||
Publisher: | Wiley-VCH Verlag GMBH | ||||
ISSN: | 1434-1948 | ||||
Official Date: | April 2011 | ||||
Dates: |
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Volume: | Vol.2011 | ||||
Number: | No.10 | ||||
Page Range: | pp. 1614-1625 | ||||
DOI: | 10.1002/ejic.201001263 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
Data sourced from Thomson Reuters' Web of Knowledge
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