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Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes
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Dallanegra, Romaeo, Robertson, Alasdair P. M., Chaplin, Adrian B., Manners, Ian and Weller, Andrew S. (2011) Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes. Chemical Communications, Vol.47 (No.13). pp. 3763-3765. doi:10.1039/c0cc05460g ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/c0cc05460g
Abstract
Efficient catalysts for the dehydrocoupling or dehydropolymerisation of H(3)B center dot NMe(x)H((3-x)) (x = 1, 2) have been developed by variation of the P-Rh-P angle in {Rh(Ph(2)P(CH(2))(n)PPh(2))}(+) fragments (n = 2-5).
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Catalysis, Phosphine, Boranes, Amines | ||||
Journal or Publication Title: | Chemical Communications | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1359-7345 | ||||
Official Date: | 7 April 2011 | ||||
Dates: |
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Volume: | Vol.47 | ||||
Number: | No.13 | ||||
Page Range: | pp. 3763-3765 | ||||
DOI: | 10.1039/c0cc05460g | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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