Dallanegra, Romaeo, Robertson, Alasdair P. M., Chaplin, Adrian B., Manners, Ian, 1961- and Weller, Andrew S.. (2011) Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes. Chemical Communications, Vol.47 (No.13). pp. 3763-3765. ISSN 1359-7345

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Abstract

Efficient catalysts for the dehydrocoupling or dehydropolymerisation of H(3)B center dot NMe(x)H((3-x)) (x = 1, 2) have been developed by variation of the P-Rh-P angle in {Rh(Ph(2)P(CH(2))(n)PPh(2))}(+) fragments (n = 2-5).

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Catalysis, Phosphine, Boranes, Amines
Journal or Publication Title:	Chemical Communications
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Date:	7 April 2011
Volume:	Vol.47
Number:	No.13
Page Range:	pp. 3763-3765
Identification Number:	10.1039/c0cc05460g
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
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URI:	http://wrap.warwick.ac.uk/id/eprint/40508

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