Chaplin, Adrian B. and Weller, Andrew S.. (2010) [B(3,5-C6H3Cl2)4]- as a useful anion for organometallic chemistry. European Journal of Inorganic Chemistry, Vol.2010 (No.32). pp. 5124-5128. ISSN 1434-1948

Full text not available from this repository.

Abstract

We highlight the use of the robust [B(3,5 C(6)H(3)Cl(2))(4)](-) anion m organometallic chemistry When partnered with organo metallic cations, compared with [BAr(4)(F)](-) it presents desirable solubility properties a lack of anion disorder in the solid state different coordinating properties with metal fragments and convenient metathetical routes for utilisation in synthesis

[error in script] [error in script]

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Rhodium, Boranes, Organometallic compounds, Organometallic chemistry, Anions
Journal or Publication Title:	European Journal of Inorganic Chemistry
Publisher:	Wiley-VCH Verlag GMBH
ISSN:	1434-1948
Date:	November 2010
Volume:	Vol.2010
Number:	No.32
Page Range:	pp. 5124-5128
Identification Number:	10.1002/ejic.201000686
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Engineering and Physical Sciences Research Council (EPSRC), University of Oxford
Grant number:	EP/E050743 (EPSRC)
References:	[1] S. H. Strauss, Chem. Rev. 1993, 93, 927–942; C. A. Reed, Acc. Chem. Res. 1998, 31, 133–139; I. Krossing, I. Raabe, Angew. 5128 www.eurjic.org © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Eur. J. Inorg. Chem. 2010, 5124–5128 Chem. Int. Ed. 2004, 43, 2066–2090; A. Macchioni, Chem. Rev. 2005, 105, 2039–2073; E. Y. X. Chen, T. J. Marks, Chem. Rev. 2000, 100, 1391–1434; G. L. Moxham, T. M. Douglas, S. K. Brayshaw, G. Kociok-Kohn, J. P. Lowe, A. S. Weller, Dalton Trans. 2006, 5492–5505. [2] K. Matsumoto, Y. Sano, M. Kawano, H. Uemura, J. Matsunami, T. Sato, Bull. Chem. Soc. Jpn. 1997, 70, 1239–1244; R. L. Paul, A. J. Amoroso, P. L. Jones, S. M. Couchman, Z. R. Reeves, L. H. Rees, J. C. Jeffery, J. A. McCleverty, M. D. Ward, J. Chem. Soc., Dalton Trans. 1999, 1563–1568; S. Kannan, M. A. Moody, C. L. Barnes, P. B. Duval, Inorg. Chem. 2006, 45, 9206–9212. [3] A. Bernsdorf, H. Brand, R. Hellmann, M. Kockerling, A. Schulz, A. Villinger, K. Voss, J. Am. Chem. Soc. 2009, 131, 8958–8970; M. H. Hannant, J. A. Wright, S. J. Lancaster, D. L. Hughes, P. N. Horton, M. Bochmann, Dalton Trans. 2006, 2415–2426. [4] I. Krossing, A. Reisinger, Coord. Chem. Rev. 2006, 250, 2721– 2744; J. M. Slattery, A. Higelin, T. Bayer, I. Krossing, Angew. Chem. Int. Ed. 2010, 49, 3228–3231. [5] C. A. Reed, Chem. Commun. 2005, 1669–1677; C. A. Reed, Acc. Chem. Res. 2010, 43, 121–128. [6] S. Korbe, P. J. Schreiber, J. Michl, Chem. Rev. 2006, 106, 5208– 5249; V. Geis, K. Guttsche, C. Knapp, H. Scherer, R. Uzun, Dalton Trans. 2009, 2687–2694. [7] E. Molinos, S. K. Brayshaw, G. Kociok-Köhn, A. S. Weller, Organometallics 2007, 26, 2370–2382. [8] A. B. Chaplin, A. S. Weller, Organometallics 2010, 29, 2332– 2342. [9] S. K. Brayshaw, J. C. Green, G. Kociok-Kohn, E. L. Sceats, A. S. Weller, Angew. Chem. Int. Ed. 2006, 45, 452–456. [10] G. E. Pacey, Anal. Chim. Acta 1980, 115, 417–420. [11] R. Anulewicz-Ostrowska, T. Klis, D. Krajewski, B. Lewandowski, J. Serwatowski, Tetrahedron Lett. 2003, 44, 7329–7331. [12] During the preparation of this manuscript, we gifted a sample of Na[BArCl2 4] for the use in the structural determination of a reactive organometallic species: D. A. Addy, G. A. Pierce, D. Vidovic, D. Mallick, E. D. Jemmis, J. M. Goicoechea, S. Aldridge, J. Am. Chem. Soc. 2010, 132, 4586. [13] a) T. M. Douglas, E. Molinos, S. K. Brayshaw, A. S. Weller, Organometallics 2007, 26, 463–465; b) S. Moret, R. Dallanegra, A. B. Chaplin, T. M. Douglas, R. M. Hiney, A. S. Weller, Inorg. Chim. Acta 2010, 363, 574–580. [14] P. Albano, M. Aresta, M. Manassero, Inorg. Chem. 1980, 19, 1069–1072; M. Bochmann, Angew. Chem. Int. Ed. Engl. 1992, 31, 1181–1182. [15] T. M. Douglas, A. B. Chaplin, A. S. Weller, Organometallics 2008, 27, 2918–2921. [16] R. Martin, S. L. Buchwald, Acc. Chem. Res. 2008, 41, 1461– 1473; F. Barrios-Landeros, B. P. Carrow, J. F. Hartwig, J. Am. Chem. Soc. 2009, 131, 8141–8154. [17] A. B. Pangborn, M. A. Giardello, R. H. Grubbs, R. K. Rosen, F. J. Timmers, Organometallics 1996, 15, 1518–1520. [18] J. Cosier, A. M. Glazer, J. Appl. Crystallogr. 1986, 19, 105–107. [19] Z. Otwinowski, W. Minor, Methods Enzymol. 1997, 276, 307– 326. [20] M. C. Burla, R. Caliandro, M. Camalli, B. Carrozzini, G. L. Cascarano, L. De Caro, C. Giacovazzo, G. Polidori, R. Spagna, J. Appl. Crystallogr. 2005, 38, 381–388. [21] G. M. Sheldrick, Acta Crystallogr., Sect. A 2008, 64, 112–122. [22] L. Farrugia, J. Appl. Crystallogr. 1997, 30, 565–565.
URI:	http://wrap.warwick.ac.uk/id/eprint/40512

Data sourced from Thomson Reuters' Web of Knowledge

Request changes to a record

Actions (login required)

View Item