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[B(3,5-C6H3Cl2)4]- as a useful anion for organometallic chemistry

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Chaplin, Adrian B. and Weller, Andrew S. (2010) [B(3,5-C6H3Cl2)4]- as a useful anion for organometallic chemistry. European Journal of Inorganic Chemistry, Vol.2010 (No.32). pp. 5124-5128. doi:10.1002/ejic.201000686

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Official URL: http://dx.doi.org/10.1002/ejic.201000686

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Abstract

We highlight the use of the robust [B(3,5 C(6)H(3)Cl(2))(4)](-) anion m organometallic chemistry When partnered with organo metallic cations, compared with [BAr(4)(F)](-) it presents desirable solubility properties a lack of anion disorder in the solid state different coordinating properties with metal fragments and convenient metathetical routes for utilisation in synthesis

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Rhodium, Boranes, Organometallic compounds, Organometallic chemistry, Anions
Journal or Publication Title: European Journal of Inorganic Chemistry
Publisher: Wiley-VCH Verlag GMBH
ISSN: 1434-1948
Official Date: November 2010
Dates:
DateEvent
November 2010Published
Volume: Vol.2010
Number: No.32
Page Range: pp. 5124-5128
DOI: 10.1002/ejic.201000686
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Engineering and Physical Sciences Research Council (EPSRC), University of Oxford
Grant number: EP/E050743 (EPSRC)

Data sourced from Thomson Reuters' Web of Knowledge

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