The Library

[B(3,5-C6H3Cl2)4]- as a useful anion for organometallic chemistry

Tools

Chaplin, Adrian B. and Weller, Andrew S.. (2010) [B(3,5-C6H3Cl2)4]- as a useful anion for organometallic chemistry. European Journal of Inorganic Chemistry, Vol.2010 (No.32). pp. 5124-5128. ISSN 1434-1948

Full text not available from this repository.

Official URL: http://dx.doi.org/10.1002/ejic.201000686

Abstract

We highlight the use of the robust [B(3,5 C(6)H(3)Cl(2))(4)](-) anion m organometallic chemistry When partnered with organo metallic cations, compared with [BAr(4)(F)](-) it presents desirable solubility properties a lack of anion disorder in the solid state different coordinating properties with metal fragments and convenient metathetical routes for utilisation in synthesis

Item Type:

Journal Article

Subjects:

Q Science > QD Chemistry

Divisions:

Faculty of Science > Chemistry

Library of Congress Subject Headings (LCSH):

Rhodium, Boranes, Organometallic compounds, Organometallic chemistry, Anions

Journal or Publication Title:

European Journal of Inorganic Chemistry

Publisher:

Wiley-VCH Verlag GMBH

ISSN:

1434-1948

Official Date:

November 2010

Dates:

Date	Event
November 2010	Published

Volume:

Vol.2010

Number:

No.32

Page Range:

pp. 5124-5128

Identification Number:

10.1002/ejic.201000686

Status:

Peer Reviewed

Publication Status:

Published

Access rights to Published version:

Restricted or Subscription Access

Funder:

Engineering and Physical Sciences Research Council (EPSRC), University of Oxford

Grant number:

EP/E050743 (EPSRC)

References:

[1] S. H. Strauss, Chem. Rev. 1993, 93, 927–942; C. A. Reed, Acc.
Chem. Res. 1998, 31, 133–139; I. Krossing, I. Raabe, Angew.
5128 www.eurjic.org © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Eur. J. Inorg. Chem. 2010, 5124–5128
Chem. Int. Ed. 2004, 43, 2066–2090; A. Macchioni, Chem. Rev.
2005, 105, 2039–2073; E. Y. X. Chen, T. J. Marks, Chem. Rev.
2000, 100, 1391–1434; G. L. Moxham, T. M. Douglas, S. K.
Brayshaw, G. Kociok-Kohn, J. P. Lowe, A. S. Weller, Dalton
Trans. 2006, 5492–5505.
[2] K. Matsumoto, Y. Sano, M. Kawano, H. Uemura, J. Matsunami,
T. Sato, Bull. Chem. Soc. Jpn. 1997, 70, 1239–1244; R. L.
Paul, A. J. Amoroso, P. L. Jones, S. M. Couchman, Z. R.
Reeves, L. H. Rees, J. C. Jeffery, J. A. McCleverty, M. D. Ward,
J. Chem. Soc., Dalton Trans. 1999, 1563–1568; S. Kannan,
M. A. Moody, C. L. Barnes, P. B. Duval, Inorg. Chem. 2006,
45, 9206–9212.
[3] A. Bernsdorf, H. Brand, R. Hellmann, M. Kockerling, A.
Schulz, A. Villinger, K. Voss, J. Am. Chem. Soc. 2009, 131,
8958–8970; M. H. Hannant, J. A. Wright, S. J. Lancaster, D. L.
Hughes, P. N. Horton, M. Bochmann, Dalton Trans. 2006,
2415–2426.
[4] I. Krossing, A. Reisinger, Coord. Chem. Rev. 2006, 250, 2721–
2744; J. M. Slattery, A. Higelin, T. Bayer, I. Krossing, Angew.
Chem. Int. Ed. 2010, 49, 3228–3231.
[5] C. A. Reed, Chem. Commun. 2005, 1669–1677; C. A. Reed,
Acc. Chem. Res. 2010, 43, 121–128.
[6] S. Korbe, P. J. Schreiber, J. Michl, Chem. Rev. 2006, 106, 5208–
5249; V. Geis, K. Guttsche, C. Knapp, H. Scherer, R. Uzun,
Dalton Trans. 2009, 2687–2694.
[7] E. Molinos, S. K. Brayshaw, G. Kociok-Köhn, A. S. Weller, Organometallics
2007, 26, 2370–2382.
[8] A. B. Chaplin, A. S. Weller, Organometallics 2010, 29, 2332–
2342.
[9] S. K. Brayshaw, J. C. Green, G. Kociok-Kohn, E. L. Sceats,
A. S. Weller, Angew. Chem. Int. Ed. 2006, 45, 452–456.
[10] G. E. Pacey, Anal. Chim. Acta 1980, 115, 417–420.
[11] R. Anulewicz-Ostrowska, T. Klis, D. Krajewski, B. Lewandowski,
J. Serwatowski, Tetrahedron Lett. 2003, 44, 7329–7331.
[12] During the preparation of this manuscript, we gifted a sample
of Na[BArCl2
4] for the use in the structural determination of
a reactive organometallic species: D. A. Addy, G. A. Pierce, D.
Vidovic, D. Mallick, E. D. Jemmis, J. M. Goicoechea, S. Aldridge,
J. Am. Chem. Soc. 2010, 132, 4586.
[13] a) T. M. Douglas, E. Molinos, S. K. Brayshaw, A. S. Weller,
Organometallics 2007, 26, 463–465; b) S. Moret, R. Dallanegra,
A. B. Chaplin, T. M. Douglas, R. M. Hiney, A. S. Weller, Inorg.
Chim. Acta 2010, 363, 574–580.
[14] P. Albano, M. Aresta, M. Manassero, Inorg. Chem. 1980, 19,
1069–1072; M. Bochmann, Angew. Chem. Int. Ed. Engl. 1992,
31, 1181–1182.
[15] T. M. Douglas, A. B. Chaplin, A. S. Weller, Organometallics
2008, 27, 2918–2921.
[16] R. Martin, S. L. Buchwald, Acc. Chem. Res. 2008, 41, 1461–
1473; F. Barrios-Landeros, B. P. Carrow, J. F. Hartwig, J. Am.
Chem. Soc. 2009, 131, 8141–8154.
[17] A. B. Pangborn, M. A. Giardello, R. H. Grubbs, R. K. Rosen,
F. J. Timmers, Organometallics 1996, 15, 1518–1520.
[18] J. Cosier, A. M. Glazer, J. Appl. Crystallogr. 1986, 19, 105–107.
[19] Z. Otwinowski, W. Minor, Methods Enzymol. 1997, 276, 307–
326.
[20] M. C. Burla, R. Caliandro, M. Camalli, B. Carrozzini, G. L.
Cascarano, L. De Caro, C. Giacovazzo, G. Polidori, R.
Spagna, J. Appl. Crystallogr. 2005, 38, 381–388.
[21] G. M. Sheldrick, Acta Crystallogr., Sect. A 2008, 64, 112–122.
[22] L. Farrugia, J. Appl. Crystallogr. 1997, 30, 565–565.