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Reversible C–H activation of a PtBuiBu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation
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Sewell, Laura J., Chaplin, Adrian B., Abdallah, Joseph A. B. and Weller, Andrew S. (2010) Reversible C–H activation of a PtBuiBu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. Dalton Transactions, Vol.39 (No.32). pp. 7437-7439. doi:10.1039/c0dt00449a
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Official URL: http://dx.doi.org/10.1039/c0dt00449a
Abstract
[Rh(P(t)Bu(i)Bu(2))(2)][BAr(4)(F)], formed by removal of H(2) from [RhH(2)(P(t)Bu(i)Bu(2))(2)][BArF(4)] is in rapid equilibrium between C-H activated Rh(III) isomers, but reacts as a masked 12-electron [Rh(P(t)Bu(i)Bu(2))(2)](+) Rh(t) cation.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Activation (Chemistry), Organometallic compounds, Hydrocarbons, Ligands, Phosphine | ||||
| Journal or Publication Title: | Dalton Transactions | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1477-9226 | ||||
| Official Date: | 28 August 2010 | ||||
| Dates: |
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| Volume: | Vol.39 | ||||
| Number: | No.32 | ||||
| Page Range: | pp. 7437-7439 | ||||
| DOI: | 10.1039/c0dt00449a | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Engineering and Physical Sciences Research Council (EPSRC), University of Oxford |
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