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Reversible C–H activation of a PtBuiBu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation

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Sewell, Laura J., Chaplin, Adrian B., Abdallah, Joseph A. B. and Weller, Andrew S.. (2010) Reversible C–H activation of a PtBuiBu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. Dalton Transactions, Vol.39 (No.32). pp. 7437-7439. ISSN 1477-9226

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Abstract

[Rh(P(t)Bu(i)Bu(2))(2)][BAr(4)(F)], formed by removal of H(2) from [RhH(2)(P(t)Bu(i)Bu(2))(2)][BArF(4)] is in rapid equilibrium between C-H activated Rh(III) isomers, but reacts as a masked 12-electron [Rh(P(t)Bu(i)Bu(2))(2)](+) Rh(t) cation.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Activation (Chemistry), Organometallic compounds, Hydrocarbons, Ligands, Phosphine
Journal or Publication Title: Dalton Transactions
Publisher: Royal Society of Chemistry
ISSN: 1477-9226
Official Date: 28 August 2010
Volume: Vol.39
Number: No.32
Page Range: pp. 7437-7439
Identification Number: 10.1039/c0dt00449a
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Engineering and Physical Sciences Research Council (EPSRC), University of Oxford
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URI: http://wrap.warwick.ac.uk/id/eprint/40514

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