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Reversible C–H activation of a PtBuiBu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation

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Sewell, Laura J., Chaplin, Adrian B., Abdallah, Joseph A. B. and Weller, Andrew S.. (2010) Reversible C–H activation of a PtBuiBu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. Dalton Transactions, Vol.39 (No.32). pp. 7437-7439. ISSN 1477-9226

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Official URL: http://dx.doi.org/10.1039/c0dt00449a

Abstract

[Rh(P(t)Bu(i)Bu(2))(2)][BAr(4)(F)], formed by removal of H(2) from [RhH(2)(P(t)Bu(i)Bu(2))(2)][BArF(4)] is in rapid equilibrium between C-H activated Rh(III) isomers, but reacts as a masked 12-electron [Rh(P(t)Bu(i)Bu(2))(2)](+) Rh(t) cation.

Item Type:

Journal Article

Subjects:

Q Science > QD Chemistry

Divisions:

Faculty of Science > Chemistry

Library of Congress Subject Headings (LCSH):

Activation (Chemistry), Organometallic compounds, Hydrocarbons, Ligands, Phosphine

Journal or Publication Title:

Dalton Transactions

Publisher:

Royal Society of Chemistry

ISSN:

1477-9226

Official Date:

28 August 2010

Dates:

Date	Event
28 August 2010	Published

Volume:

Vol.39

Number:

No.32

Page Range:

pp. 7437-7439

Identification Number:

10.1039/c0dt00449a

Status:

Peer Reviewed

Publication Status:

Published

Access rights to Published version:

Restricted or Subscription Access

Funder:

Engineering and Physical Sciences Research Council (EPSRC), University of Oxford

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