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Isolation of a low-coordinate rhodium phosphine complex formed by C−C bond activation of biphenylene
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Chaplin, Adrian B., Tonner, Ralf and Weller, Andrew S. (2010) Isolation of a low-coordinate rhodium phosphine complex formed by C−C bond activation of biphenylene. Organometallics, Vol.29 (No.12). pp. 2710-2714. doi:10.1021/om100149w
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Official URL: http://dx.doi.org/10.1021/om100149w
Abstract
The isolation of a low-coordinate rhodium complex containing the 2,2'-biphenyl ligand, trans-{Rh(2,2'-biphenyl)(P(i)Pr(3)),][BAr(4)(F)], is described. This complex is prepared by C C bond activation of biphenylene by the [Rh(P(i)Pr(3))(2)](+) fragment and proceeds via the (isolated) intermediate pi complex [Rh(eta(6)-biphenylene)(P(i)Pr(3))(2)[BAr(4)(F)]. An intramolecular ring slippage mechanism is suggested for this process, and this is supported by DET calculations.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Activation (Chemistry), Rhodium, Phosphine, Chemical bonds, Organometallic compounds | ||||
| Journal or Publication Title: | Organometallics | ||||
| Publisher: | American Chemical Society | ||||
| ISSN: | 0276-7333 | ||||
| Official Date: | 28 June 2010 | ||||
| Dates: |
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| Volume: | Vol.29 | ||||
| Number: | No.12 | ||||
| Page Range: | pp. 2710-2714 | ||||
| DOI: | 10.1021/om100149w | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Engineering and Physical Sciences Research Council (EPSRC), University of Oxford, Alexander von Humboldt-Stiftung |
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