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Isolation of a low-coordinate rhodium phosphine complex formed by C−C bond activation of biphenylene

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Chaplin, Adrian B., Tonner, Ralf and Weller, Andrew S. (2010) Isolation of a low-coordinate rhodium phosphine complex formed by C−C bond activation of biphenylene. Organometallics, Vol.29 (No.12). pp. 2710-2714. doi:10.1021/om100149w ISSN 0276-7333.

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Official URL: http://dx.doi.org/10.1021/om100149w

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Abstract

The isolation of a low-coordinate rhodium complex containing the 2,2'-biphenyl ligand, trans-{Rh(2,2'-biphenyl)(P(i)Pr(3)),][BAr(4)(F)], is described. This complex is prepared by C C bond activation of biphenylene by the [Rh(P(i)Pr(3))(2)](+) fragment and proceeds via the (isolated) intermediate pi complex [Rh(eta(6)-biphenylene)(P(i)Pr(3))(2)[BAr(4)(F)]. An intramolecular ring slippage mechanism is suggested for this process, and this is supported by DET calculations.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Library of Congress Subject Headings (LCSH): Activation (Chemistry), Rhodium, Phosphine, Chemical bonds, Organometallic compounds
Journal or Publication Title: Organometallics
Publisher: American Chemical Society
ISSN: 0276-7333
Official Date: 28 June 2010
Dates:
DateEvent
28 June 2010Published
Volume: Vol.29
Number: No.12
Page Range: pp. 2710-2714
DOI: 10.1021/om100149w
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Engineering and Physical Sciences Research Council (EPSRC), University of Oxford, Alexander von Humboldt-Stiftung

Data sourced from Thomson Reuters' Web of Knowledge

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