Dallanegra, Romaeo, Chaplin, Adrian B., Tsim, Jennifer and Weller, Andrew S.. (2010) Amino-borane oligomers bound to a Rh(i) metal fragment. Chemical Communications, Vol.46 (No.18). pp. 3092-3094. ISSN 1359-7345

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Abstract

Coordination complexes of previously observed intermediates, H(3)B center dot NMe(2)BH(2)center dot NMe(2)H and [H(2)BNMeH](3), in the transition metal catalysed dehydrocoupling of H(3)B center dot NMe(2)H and H(3)B center dot NMeH(2) have been isolated and structurally characterised using the [Rh{PR(2)'(eta(2)-C(5)H(7))}](+) fragment. Their onward reactivity shows that further dehydrogenation is not a simple intramolecular process.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Boranes, Amines, Complex compounds, Oligomers, Rhodium, Catalysis, Dehydrogenation
Journal or Publication Title:	Chemical Communications
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Date:	14 May 2010
Volume:	Vol.46
Number:	No.18
Page Range:	pp. 3092-3094
Identification Number:	10.1039/c003055d
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
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URI:	http://wrap.warwick.ac.uk/id/eprint/40518

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