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B-H activation at a rhodium(I) center : isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes
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Chaplin, Adrian B. and Weller, Andrew S. (2009) B-H activation at a rhodium(I) center : isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes. Angewandte Chemie International Edition, Vol.49 (No.3). pp. 581-584. doi:10.1002/anie.200905185 ISSN 1433-7851.
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Official URL: http://dx.doi.org/10.1002/anie.200905185
Abstract
The missing link: A bimetallic complex that is relevant to the mechanism of transition-metal-catalyzed amine–borane dehydrocoupling has been isolated. The structure (see picture) contains three different amine–borane activation modes within the same molecule.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Transition metal catalysts, Boranes, Addition reactions, Rhodium, X-rays -- Diffraction, Amines | ||||
Journal or Publication Title: | Angewandte Chemie International Edition | ||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
ISSN: | 1433-7851 | ||||
Official Date: | 2009 | ||||
Dates: |
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Volume: | Vol.49 | ||||
Number: | No.3 | ||||
Page Range: | pp. 581-584 | ||||
DOI: | 10.1002/anie.200905185 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC) |
Data sourced from Thomson Reuters' Web of Knowledge
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