Chaplin, Adrian B. and Weller, Andrew S.. (2009) B-H activation at a rhodium(I) center : isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes. Angewandte Chemie International Edition, Vol.49 (No.3). pp. 581-584. ISSN 1433-7851

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Abstract

The missing link: A bimetallic complex that is relevant to the mechanism of transition-metal-catalyzed amine–borane dehydrocoupling has been isolated. The structure (see picture) contains three different amine–borane activation modes within the same molecule.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Transition metal catalysts, Boranes, Addition reactions, Rhodium, X-rays -- Diffraction, Amines
Journal or Publication Title:	Angewandte Chemie International Edition
Publisher:	Wiley - V C H Verlag GmbH & Co. KGaA
ISSN:	1433-7851
Date:	2009
Volume:	Vol.49
Number:	No.3
Page Range:	pp. 581-584
Identification Number:	10.1002/anie.200905185
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Engineering and Physical Sciences Research Council (EPSRC)
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URI:	http://wrap.warwick.ac.uk/id/eprint/40526

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