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Bis(σ-amine-borane) complexes : an unusual binding mode at a transition-metal center

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Dallanegra, Romaeo, Chaplin, Adrian B. and Weller, Andrew S. (2009) Bis(σ-amine-borane) complexes : an unusual binding mode at a transition-metal center. Angewandte Chemie International Edition, Vol.48 (No.37). pp. 6875-6878. doi:10.1002/anie.200903121 ISSN 1433-7851.

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Official URL: http://dx.doi.org/10.1002/anie.200903121

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Abstract

Getting a fix: Bis(σ-amine–borane) rhodium complexes featuring a new binding mode (two amine–borane ligands) have been prepared (see picture; Rh yellow, P green, B pink, N blue). These complexes undergo dehydrocoupling to afford di- or trimeric cyclic aminoboryl products.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Library of Congress Subject Headings (LCSH): Amines, Boranes, Rhodium, Dehydrogenation, Catalysis, Transition metal catalysts, Coordination compounds
Journal or Publication Title: Angewandte Chemie International Edition
Publisher: Wiley - V C H Verlag GmbH & Co. KGaA
ISSN: 1433-7851
Official Date: 1 September 2009
Dates:
DateEvent
1 September 2009Published
Volume: Vol.48
Number: No.37
Page Range: pp. 6875-6878
DOI: 10.1002/anie.200903121
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Engineering and Physical Sciences Research Council (EPSRC), University of Oxford

Data sourced from Thomson Reuters' Web of Knowledge

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