Dallanegra, Romaeo, Chaplin, Adrian B. and Weller, Andrew S.. (2009) Bis(σ-amine-borane) complexes : an unusual binding mode at a transition-metal center. Angewandte Chemie International Edition, Vol.48 (No.37). pp. 6875-6878. ISSN 1433-7851

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Abstract

Getting a fix: Bis(σ-amine–borane) rhodium complexes featuring a new binding mode (two amine–borane ligands) have been prepared (see picture; Rh yellow, P green, B pink, N blue). These complexes undergo dehydrocoupling to afford di- or trimeric cyclic aminoboryl products.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Amines, Boranes, Rhodium, Dehydrogenation, Catalysis, Transition metal catalysts, Coordination compounds
Journal or Publication Title:	Angewandte Chemie International Edition
Publisher:	Wiley - V C H Verlag GmbH & Co. KGaA
ISSN:	1433-7851
Date:	1 September 2009
Volume:	Vol.48
Number:	No.37
Page Range:	pp. 6875-6878
Identification Number:	10.1002/anie.200903121
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Engineering and Physical Sciences Research Council (EPSRC), University of Oxford
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URI:	http://wrap.warwick.ac.uk/id/eprint/40530

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