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Bis(σ-amine-borane) complexes : an unusual binding mode at a transition-metal center
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Dallanegra, Romaeo, Chaplin, Adrian B. and Weller, Andrew S. (2009) Bis(σ-amine-borane) complexes : an unusual binding mode at a transition-metal center. Angewandte Chemie International Edition, Vol.48 (No.37). pp. 6875-6878. doi:10.1002/anie.200903121 ISSN 1433-7851.
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Official URL: http://dx.doi.org/10.1002/anie.200903121
Abstract
Getting a fix: Bis(σ-amine–borane) rhodium complexes featuring a new binding mode (two amine–borane ligands) have been prepared (see picture; Rh yellow, P green, B pink, N blue). These complexes undergo dehydrocoupling to afford di- or trimeric cyclic aminoboryl products.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Amines, Boranes, Rhodium, Dehydrogenation, Catalysis, Transition metal catalysts, Coordination compounds | ||||
| Journal or Publication Title: | Angewandte Chemie International Edition | ||||
| Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
| ISSN: | 1433-7851 | ||||
| Official Date: | 1 September 2009 | ||||
| Dates: |
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| Volume: | Vol.48 | ||||
| Number: | No.37 | ||||
| Page Range: | pp. 6875-6878 | ||||
| DOI: | 10.1002/anie.200903121 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Engineering and Physical Sciences Research Council (EPSRC), University of Oxford |
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