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Bis(σ-amine-borane) complexes : an unusual binding mode at a transition-metal center
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Dallanegra, Romaeo, Chaplin, Adrian B. and Weller, Andrew S. (2009) Bis(σ-amine-borane) complexes : an unusual binding mode at a transition-metal center. Angewandte Chemie International Edition, Vol.48 (No.37). pp. 6875-6878. doi:10.1002/anie.200903121 ISSN 1433-7851.
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Official URL: http://dx.doi.org/10.1002/anie.200903121
Abstract
Getting a fix: Bis(σ-amine–borane) rhodium complexes featuring a new binding mode (two amine–borane ligands) have been prepared (see picture; Rh yellow, P green, B pink, N blue). These complexes undergo dehydrocoupling to afford di- or trimeric cyclic aminoboryl products.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Amines, Boranes, Rhodium, Dehydrogenation, Catalysis, Transition metal catalysts, Coordination compounds | ||||
Journal or Publication Title: | Angewandte Chemie International Edition | ||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
ISSN: | 1433-7851 | ||||
Official Date: | 1 September 2009 | ||||
Dates: |
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Volume: | Vol.48 | ||||
Number: | No.37 | ||||
Page Range: | pp. 6875-6878 | ||||
DOI: | 10.1002/anie.200903121 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC), University of Oxford |
Data sourced from Thomson Reuters' Web of Knowledge
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