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Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides
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Douglas, Thomas M., Chaplin, Adrian B. and Weller, Andrew S. (2008) Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides. Organometallics, Vol.27 (No.13). pp. 2918-2921. doi:10.1021/om800373d
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Official URL: http://dx.doi.org/10.1021/om800373d
Abstract
Dihydrogen loss from the 14-electron Rh(III) bisphosphine dihydride [Rh((PBu3)-Bu-i)(2)H-2][BAr4F] forms a complex tentatively identified as [Rh((PBu3)-Bu-i)(2)(L-2)][BAr4F] (L-2 = solvent or agostic interactions), which reacts with dichloroethane or fluorobenzene to form [Rh((PBu3)-Bu-i)(2)(ClCH2CH2Cl)][BAr4F] and [Rh((PBu3)-Bu-i)(2)(eta(6)-C6H5F)][BAr4F], respectively. [Rh(PiBu(3))(2)(L)(2)][BAr4F] or its adducts undergo oxidative addition of aryl halides (C6H5X; X = Cl, Br) at room temperature to give the dimeric species [Rh(PiBu3)(2)(C6H5)(mu-X)](2).
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Addition reactions, Phosphine, Rhodium, Transition metal complexes, Organometallic chemistry, Halides | ||||
| Journal or Publication Title: | Organometallics | ||||
| Publisher: | American Chemical Society | ||||
| ISSN: | 0276-7333 | ||||
| Official Date: | 14 July 2008 | ||||
| Dates: |
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| Volume: | Vol.27 | ||||
| Number: | No.13 | ||||
| Page Range: | pp. 2918-2921 | ||||
| DOI: | 10.1021/om800373d | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Engineering and Physical Sciences Research Council (EPSRC), University of Oxford |
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