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Linked metal-cluster systems : isolation and characterisation of {anti-[(p-cymene)RuCl]-μ-[κ 2-P,P′;κ 1-P′′-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2

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Chaplin, Adrian B., Béni, Zoltán, Hartinger, Christian G., Hamidane, Hisham Ben, Phillips, Andrew D., Scopelliti, Rosario and Dyson, Paul J.. (2008) Linked metal-cluster systems : isolation and characterisation of {anti-[(p-cymene)RuCl]-μ-[κ 2-P,P′;κ 1-P′′-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2. Journal of Cluster Science, Vol.19 (No.1). pp. 295-309. ISSN 1040-7278

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Abstract

The new mixed-metal complex {anti-[(p-cymene)RuCl]-mu-[kappa(2)-P,P';kappa(1)-P''-(PPh(2)CH(2))(3)CMe]-[AuCl]}PF(6) and its cluster derivative {anti-[(p-cymene)RuCl]-mu-[kappa(2)-P,P';kappa(1)-P''-(PPh(2)CH(2))(3)CMe]-[AuPt(3)(CO)(3)(PCy(3))(3)]}(PF(6))(2) have been prepared and characterized. Notably, NMR spectroscopy and high resolution FT-ICR mass spectrometry, including a tandem mass spectrometric analysis, demonstrated the formation of these compounds that was also confirmed by single crystal X-ray diffraction analysis.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Metal clusters, Platinum
Journal or Publication Title: Journal of Cluster Science
Publisher: Springer New York LLC
ISSN: 1040-7278
Official Date: March 2008
Volume: Vol.19
Number: No.1
Page Range: pp. 295-309
Identification Number: 10.1007/s10876-007-0175-0
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: École polytechnique fédérale de Lausanne [Swiss Federal Institute of Technology] (EPFL), Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung [Swiss National Science Foundation] (SNF)
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URI: http://wrap.warwick.ac.uk/id/eprint/40541

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