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Linked metal-cluster systems : isolation and characterisation of {anti-[(p-cymene)RuCl]-μ-[κ 2-P,P′;κ 1-P′′-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2

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Chaplin, Adrian B., Béni, Zoltán, Hartinger, Christian G., Hamidane, Hisham Ben, Phillips, Andrew D., Scopelliti, Rosario and Dyson, Paul J.. (2008) Linked metal-cluster systems : isolation and characterisation of {anti-[(p-cymene)RuCl]-μ-[κ 2-P,P′;κ 1-P′′-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2. Journal of Cluster Science, Vol.19 (No.1). pp. 295-309. ISSN 1040-7278

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Official URL: http://dx.doi.org/10.1007/s10876-007-0175-0

Abstract

The new mixed-metal complex {anti-[(p-cymene)RuCl]-mu-[kappa(2)-P,P';kappa(1)-P''-(PPh(2)CH(2))(3)CMe]-[AuCl]}PF(6) and its cluster derivative {anti-[(p-cymene)RuCl]-mu-[kappa(2)-P,P';kappa(1)-P''-(PPh(2)CH(2))(3)CMe]-[AuPt(3)(CO)(3)(PCy(3))(3)]}(PF(6))(2) have been prepared and characterized. Notably, NMR spectroscopy and high resolution FT-ICR mass spectrometry, including a tandem mass spectrometric analysis, demonstrated the formation of these compounds that was also confirmed by single crystal X-ray diffraction analysis.

Item Type:

Journal Article

Subjects:

Q Science > QD Chemistry

Divisions:

Faculty of Science > Chemistry

Library of Congress Subject Headings (LCSH):

Metal clusters, Platinum

Journal or Publication Title:

Journal of Cluster Science

Publisher:

Springer New York LLC

ISSN:

1040-7278

Official Date:

March 2008

Dates:

Date	Event
March 2008	Published

Volume:

Vol.19

Number:

No.1

Page Range:

pp. 295-309

Identifier:

10.1007/s10876-007-0175-0

Status:

Peer Reviewed

Publication Status:

Published

Access rights to Published version:

Restricted or Subscription Access

Funder:

École polytechnique fédérale de Lausanne [Swiss Federal Institute of Technology] (EPFL), Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung [Swiss National Science Foundation] (SNF)

References:

1. For example see, (a) P. Braunstein, L. Oro, and P. R. Raithby (eds.), Metal Clusters in Chemistry
(Wiley-VCH, Weinheim, 1999). (b) P. J. Dyson and J. S. McIndoe (eds.), Transition Metal Carbonyl
Cluster Chemistry (Gordon and Breach Science Publishers, 2000).
2. P. J. Dyson (1999). Adv. Organomet. Chem. 43, 43. In this review the use of Me3NO is extensively
discussed.
3. (a) W. L. Gladfelter, and G. L. Geoffroy (1980). Adv. Organomet. Chem. 18, 207. (b) L. J. Farrugia
(1990). Adv. Organomet. Chem. 31, 301. (c) K. H. Whitmire (1998). Adv. Organomet. Chem. 42, 1.
4. (a) R. D. Adams, B. Captain, W. Fu, and M. D. Smith (2002). J. Am. Chem. Soc. 124, 5628. (b) R. D.
Adams, B. Captain, W. Fu, M. B. Hall, J. Manson, M. D. Smith, and C. E. Webster (2004). J. Am.
Chem. Soc. 126, 5253. (c) R. D. Adams, B. Captain, P. J. Pellechia, and M. D. Smith (2004). Inorg.
Chem. 43, 3921. (d) R. D. Adams, B. Captain, M. B. Hall, J. L. Smith, Jr., and C. E. Webster (2005).
J. Am. Chem. Soc. 127, 1007.
5. L. H. Gade (1993). Angew. Chem. Int. Ed. 32, 24.
6. I. D. Salter (1989). Adv. Organomet. Chem. 29, 249.
7. D. G. Evans, D. M. P. Mingos (1982). J. Organomet. Chem. 232, 171.
8. S. W. A. Fong and T. S. A. Hor (1998). J. Clust. Sci. 9, 351.
9. D. S. Shephard, B. F. G. Johnson, A. Harrison, S. Parsons, S. P. Smidt, L. J. Yellowlees, and D. Reed
(1998). J. Organomet. Chem. 563, 113.
10. For example, see: (a) E. Louattani, J. Suades, K. Urtiaga, M. I. Arriortua, and X. Solans (1996).
Organometallics 15, 468. (b) N. E. Leadbeater, J. Lewis, P. R. Raithby, and A. J. Edwards (1997). J.
Organomet. Chem. 545–546, 567. (c) N. T. Lucas, M. P. Cifuentes, L. T. Nguyen, and M. G.
Humphrey (2001). J. Clust. Sci. 12, 201. (d) W.-Y. Yeh, C.-I. Li, S.-M. Peng, and G.-H. Lee (2004).
J. Organomet. Chem. 689, 105.
11. X. Lei, E. E. Wolf, and T. P. Fehlner (1998). Eur. J. Inorg. Chem. 1835.
12. C. Boxwell, P. J. Dyson, D. J. Ellis, and T. Welton (2002). J. Am. Chem. Soc. 124, 9334.
13. A. Moor, P. S. Pregosin, and L. M. Venanzi (1981). Inorg. Chim. Acta 48, 153.
14. D. Imhof, U. Burckhardt, K.-H. Dahmen, F. Joho, and R. Nesper (1997). Inorg. Chem. 36, 1813.
15. Small deviations from the observed and calculated spectra occurs as a result of the difficulty in fitting
the 1JPtPt0 coupling constant. The effected satellites in the observed spectrum have increased line
broadening in comparison to the simulation.
16. (a) W. Henderson, J. S. McIndoe, B. K. Nicholson, and P. J. Dyson (1998). J. Chem. Soc., Dalton
Trans. 519. (b) P. J. Dyson, B. F. G. Johnson, J. S. McIndoe, and P. R. R. Langridge-Smith (2000).
Inorg. Chem. 39, 2430.
17. A. R. Timerbaev, C. G. Hartinger, S. S. Aleksenko, and B. K. Keppler (2006). Chem. Rev. 106, 2224.
18. C. G. Hartinger, W. H. Ang, A. Casini, L. Messori, B. K. Keppler, and P. J. Dyson (2007). J. Anal. At.
Spectrom. 22, 960.
19. A. Casini, G. Mastrobuoni, W. H. Ang, C. Gabbiani, G. Pieraccini, G. Moneti, P. J. Dyson, and L.
Messori (2007). ChemMedChem 2, 631.
20. N. C. Baenziger, W. E. Bennett, and D. M. Soboroff (1976). Acta Crystallogr., Sect. B: Struct.
Crystallogr. Cryst. Chem. 32, 962.
21. P. Sevollano, M. E. Garcia, A. Habtemariam, S. Parsons, and P. J. Sadler (1999). Met.-Based Drugs
6, 211.
22. E. J. Fernandez, M. C. Gimeno, P. G. Jones, A. Laguna, M. Laguna, and E. Olmos (1996). J. Chem.
Soc., Dalton Trans. 3603.
23. P. Sevillano, A. Habtemariam, M. I. G. Seijo, A. Castineiras, S. Parsons, M. E. Garcia, and P. J.
Sadler (2000). Aust. J. Chem. 53, 635.
24. C. Mealli (1982). Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 38, 1040.
25. A. Albinati (1977). Inorg. Chim. Acta. 22, L31.
26. R. Uso´n and A. Laguna, in R. Bruce and J. J. Eisch (eds.), Organometallic Syntheses, vol. 3
(Academic Press, New York, 1986), p. 322.
27. K.-H. Dahmen, A. Moor, R. Naegeli, and L. M. Venanzi (1991). Inorg. Chem. 20, 4285.
28. P. H. M. Budzelaar (1997). g-NMR v4.0, IvorySoft.
29. Oxford Diffraction. CrysAlis CCD and CrysAlis RED version 1.71, 2006, Oxford Diffraction Ltd,
Abingdon, Oxfordshire, United Kingdom.
30. Bruker-Nonius. XPREP: Reciprocal Space Exploration, version 6.14. 2003, Bruker AXS, Madison,
Wisconsin, USA.
31. G. M. Sheldrick, SHELXL-97: A program for the refinement of crystal structures. Release 6. 2003,
Institut fu¨r Anorganische Chemie der Universita¨t Go¨ttingen, Tammannstr, Germany.
32. Diamond 3.1e, Crystal and Molecular Structure Visualization Program, 2007, Crystal Impact, Bonn,
Germany.