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Linked metal-cluster systems : isolation and characterisation of {anti-[(p-cymene)RuCl]-μ-[κ 2-P,P′;κ 1-P′′-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2
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Chaplin, Adrian B., Béni, Zoltán, Hartinger, Christian G., Hamidane, Hisham Ben, Phillips, Andrew D., Scopelliti, Rosario and Dyson, Paul J. (2008) Linked metal-cluster systems : isolation and characterisation of {anti-[(p-cymene)RuCl]-μ-[κ 2-P,P′;κ 1-P′′-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2. Journal of Cluster Science, Vol.19 (No.1). pp. 295-309. doi:10.1007/s10876-007-0175-0 ISSN 1040-7278.
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Official URL: http://dx.doi.org/10.1007/s10876-007-0175-0
Abstract
The new mixed-metal complex {anti-[(p-cymene)RuCl]-mu-[kappa(2)-P,P';kappa(1)-P''-(PPh(2)CH(2))(3)CMe]-[AuCl]}PF(6) and its cluster derivative {anti-[(p-cymene)RuCl]-mu-[kappa(2)-P,P';kappa(1)-P''-(PPh(2)CH(2))(3)CMe]-[AuPt(3)(CO)(3)(PCy(3))(3)]}(PF(6))(2) have been prepared and characterized. Notably, NMR spectroscopy and high resolution FT-ICR mass spectrometry, including a tandem mass spectrometric analysis, demonstrated the formation of these compounds that was also confirmed by single crystal X-ray diffraction analysis.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Metal clusters, Platinum | ||||
Journal or Publication Title: | Journal of Cluster Science | ||||
Publisher: | Springer New York LLC | ||||
ISSN: | 1040-7278 | ||||
Official Date: | March 2008 | ||||
Dates: |
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Volume: | Vol.19 | ||||
Number: | No.1 | ||||
Page Range: | pp. 295-309 | ||||
DOI: | 10.1007/s10876-007-0175-0 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Funder: | École polytechnique fédérale de Lausanne [Swiss Federal Institute of Technology] (EPFL), Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung [Swiss National Science Foundation] (SNF) |
Data sourced from Thomson Reuters' Web of Knowledge
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