The Library
Organocatalytic synthesis and postpolymerization functionalization of allyl-functional poly(carbonate)s
Tools
Tools
Tools
Tempelaar, Sarah, Mespouille, Laetitia, Dubois, Philippe and Dove, Andrew P. (2011) Organocatalytic synthesis and postpolymerization functionalization of allyl-functional poly(carbonate)s. Macromolecules, Vol.44 (No.7). pp. 2084-2091. doi:10.1021/ma102882v ISSN 0024-9297 .
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Official URL: http://dx.doi.org/10.1021/ma102882v
Abstract
Well-defined allyl-functional poly(carbonate)s were synthesized via the organocatalytic ring-opening polymerization of 5-methyl-5-allyloxycarbonyl-1,3-dioxan-2-one using the dual 1-(3,5-bis(trifluoromethyl)phenyl)-3-cyclohexylthiourea and (−)-sparteine catalyst system. The resulting allyl-functional poly(carbonate)s obtained showed low polydispersities and high end-group fidelity, with the versatility of the system being demonstrated by the synthesis of block copolymers and telechelic polymers. Further functionalization of homopolymers with degrees of polymerization of 11 and 100 were realized via the radical addition of thiols to the pendant allyl functional groups, resulting in a range of functional aliphatic poly(carbonate)s.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry T Technology > TP Chemical technology |
||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Organic compounds -- Synthesis, Polymerization, Polycarbonates, Monomers | ||||
| Journal or Publication Title: | Macromolecules | ||||
| Publisher: | American Chemical Society | ||||
| ISSN: | 0024-9297 | ||||
| Official Date: | 12 April 2011 | ||||
| Dates: |
|
||||
| Volume: | Vol.44 | ||||
| Number: | No.7 | ||||
| Page Range: | pp. 2084-2091 | ||||
| DOI: | 10.1021/ma102882v | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Research Councils UK (RCUK), Engineering and Physical Sciences Research Council (EPSRC), Advantage West Midlands (AWM), European Regional Development Fund (ERDF), Belgium. Services fédéraux des affaires scientifiques, techniques et culturelles [Belgium. Federal Office for Scientific, Technical, and Cultural Affairs] (SSTC), Fonds national de la recherche scientifique (Belgium) (FNRS) | ||||
| Grant number: | EP/F068808/1 (EPSRC), EP/C007999/1 (EPSRC) |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
 |
View Item |
