Tempelaar, Sarah, Mespouille, Laetitia, Dubois, Philippe and Dove, Andrew P.. (2011) Organocatalytic synthesis and postpolymerization functionalization of allyl-functional poly(carbonate)s. Macromolecules, Vol.44 (No.7). pp. 2084-2091. ISSN 0024-9297

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Abstract

Well-defined allyl-functional poly(carbonate)s were synthesized via the organocatalytic ring-opening polymerization of 5-methyl-5-allyloxycarbonyl-1,3-dioxan-2-one using the dual 1-(3,5-bis(trifluoromethyl)phenyl)-3-cyclohexylthiourea and (−)-sparteine catalyst system. The resulting allyl-functional poly(carbonate)s obtained showed low polydispersities and high end-group fidelity, with the versatility of the system being demonstrated by the synthesis of block copolymers and telechelic polymers. Further functionalization of homopolymers with degrees of polymerization of 11 and 100 were realized via the radical addition of thiols to the pendant allyl functional groups, resulting in a range of functional aliphatic poly(carbonate)s.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry T Technology > TP Chemical technology
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Organic compounds -- Synthesis, Polymerization, Polycarbonates, Monomers
Journal or Publication Title:	Macromolecules
Publisher:	American Chemical Society
ISSN:	0024-9297
Date:	12 April 2011
Volume:	Vol.44
Number:	No.7
Page Range:	pp. 2084-2091
Identification Number:	10.1021/ma102882v
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Funder:	Research Councils UK (RCUK), Engineering and Physical Sciences Research Council (EPSRC), Advantage West Midlands (AWM), European Regional Development Fund (ERDF), Belgium. Services fédéraux des affaires scientifiques, techniques et culturelles [Belgium. Federal Office for Scientific, Technical, and Cultural Affairs] (SSTC), Fonds national de la recherche scientifique (Belgium) (FNRS)
Grant number:	EP/F068808/1 (EPSRC), EP/C007999/1 (EPSRC)
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URI:	http://wrap.warwick.ac.uk/id/eprint/40553

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