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Nonfouling polypeptide brushes via surface-initiated polymerization of Nε-oligo(ethylene glycol)succinate-L-lysine N-carboxyanhydride
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Wang, Jing, Gibson, Matthew I., Barbey, Raphaël, Xiao, Shou-Jun and Klok, Harm-Anton (2009) Nonfouling polypeptide brushes via surface-initiated polymerization of Nε-oligo(ethylene glycol)succinate-L-lysine N-carboxyanhydride. Macromolecular Rapid Communications, Vol.30 (No.9-10). pp. 845-850. doi:10.1002/marc.200800744 ISSN 1022-1336.
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Official URL: http://dx.doi.org/10.1002/marc.200800744
Abstract
This contribution describes the preparation of nonfouling polypeptide brushes via surface-initiated ring-opening polymerization of oligo(ethylene glycol) modified L-lysine N-carboxyanhydrides. Circular dichroism experiments indicated that these surface-anchored polypeptide chains assume an a-helical conformation, which does not change between pH 4 and 9. Furthermore, nonspecific adsorption of fluorescent labeled bovine serum albumin and fibrinogen on glass slides modified with these brushes was greatly reduced compared to unmodified glass substrates.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Polymers, Peptides, Ring-opening polymerization, Surface chemistry, Polypeptides -- Surfaces | ||||
Journal or Publication Title: | Macromolecular Rapid Communications | ||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
ISSN: | 1022-1336 | ||||
Official Date: | 19 May 2009 | ||||
Dates: |
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Volume: | Vol.30 | ||||
Number: | No.9-10 | ||||
Page Range: | pp. 845-850 | ||||
DOI: | 10.1002/marc.200800744 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Funder: | China Scholarship Council (CSC), National Construction of high-quality University projects of graduates |
Data sourced from Thomson Reuters' Web of Knowledge
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