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Platinum(iv) centres with agostic interactions from either sp2 or sp3 C–H bonds

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Crosby, Sarah H., Deeth, Robert J., Clarkson, Guy J. and Rourke, Jonathan (2011) Platinum(iv) centres with agostic interactions from either sp2 or sp3 C–H bonds. Dalton Transactions, Vol.40 (No.6). pp. 1227-1229. doi:10.1039/c0dt01428a

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Official URL: http://dx.doi.org/10.1039/c0dt01428a

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Abstract

Agostic complexes of platinum(IV) have been isolated and characterised. A Pt(II) sp(3) agostic complex maintains the agostic interaction upon oxidation giving a Pt(IV) sp(3) agostic complex; in another Pt(IV) complex the agostic interaction from an sp(2) C-H bond is sufficient to displace another ligand.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Platinum, Organometallic chemistry, Complex compounds -- Synthesis, Platinum -- Oxidation, Chemical bonds
Journal or Publication Title: Dalton Transactions
Publisher: Royal Society of Chemistry
ISSN: 1477-9226
Official Date: 2011
Dates:
DateEvent
2011Published
Volume: Vol.40
Number: No.6
Page Range: pp. 1227-1229
DOI: 10.1039/c0dt01428a
Status: Peer Reviewed
Publication Status: Published
Funder: University of Warwick, Advantage West Midlands (AWM), European Regional Development Fund (ERDF)

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