The Library

Platinum(iv) centres with agostic interactions from either sp2 or sp3 C–H bonds

Tools

Crosby, Sarah H., Deeth, Robert J., Clarkson, Guy J. and Rourke, Jonathan P.. (2011) Platinum(iv) centres with agostic interactions from either sp2 or sp3 C–H bonds. Dalton Transactions, Vol.40 (No.6). pp. 1227-1229. ISSN 1477-9226

Full text not available from this repository.

Abstract

Agostic complexes of platinum(IV) have been isolated and characterised. A Pt(II) sp(3) agostic complex maintains the agostic interaction upon oxidation giving a Pt(IV) sp(3) agostic complex; in another Pt(IV) complex the agostic interaction from an sp(2) C-H bond is sufficient to displace another ligand.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Platinum, Organometallic chemistry, Complex compounds -- Synthesis, Platinum -- Oxidation, Chemical bonds
Journal or Publication Title: Dalton Transactions
Publisher: Royal Society of Chemistry
ISSN: 1477-9226
Date: 2011
Volume: Vol.40
Number: No.6
Page Range: pp. 1227-1229
Identification Number: 10.1039/c0dt01428a
Status: Peer Reviewed
Publication Status: Published
Funder: University of Warwick, Advantage West Midlands (AWM), European Regional Development Fund (ERDF)
References: 1 M. Brookhart, M. L. H. Green and G. Parkin, Proc. Natl. Acad. Sci. U. S. A., 2007, 104, 6908–6914. 2 E. Clot and O. Eisenstein, “Agostic interactions from a computational perspective: One name, many interpretations”, In Principles and Applications of Density in Inorganic Chemistry II, 2004; Vol. 113, pp 1–36. 3 J. A. Labinger and J. E. Bercaw, Nature, 2002, 417, 507–514. 4 R. G. Bergman, Nature, 2007, 446, 391–393. 5 A. S. Goldman and K. I. Goldberg, In Activation and Functionalization of C–H Bonds, K. I. Goldberg and A. S. Goldman, ed. ACS, Washington DC, 2004; Vol. ACS Symposium Series vol 885. 6 N. Carr, B. J. Dunne, A. G. Orpen and J. L. Spencer, J. Chem. Soc., Chem. Commun., 1988, 926–928. 7 N. Carr, L. Mole, A. G. Orpen and J. L. Spencer, J. Chem. Soc., Dalton Trans., 1992, 2653–2662. 8 M. J. Ingleson, M. F. Mahon and A. S.Weller, Chem. Commun., 2004, 2398–2399. 9 S. H. Crosby, G. J. Clarkson and J. P. Rourke, J. Am. Chem. Soc., 2009, 131, 14142–14143. 10 E. Khaskin, P. Y. Zavalij and A.N. Vedernikov, Angew. Chem., Int. Ed., 2007, 46, 6309–6312. 11 P. V. Bernhardt, C. Gallego and M. Martinez, Organometallics, 2000, 19, 4862–4869. 12 U. Fekl, W. Kaminsky and K. I. Goldberg, J. Am. Chem. Soc., 2001, 123, 6423–6424. 13 U. Fekl and K. I. Goldberg, J. Am. Chem. Soc., 2002, 124, 6804– 6805. 14 U. Fekl, W. Kaminsky and K. I. Goldberg, J. Am. Chem. Soc., 2003, 125, 15286–15287. 15 D. Karshtedt, J. L.McBee, A. T. Bell and T. D. Tilley, Organometallics, 2006, 25, 1801–1811. 16 S. M. Kloek and K. I. Goldberg, J. Am. Chem. Soc., 2007, 129, 3460. 17 A. T. Luedtke and K. I. Goldberg, Inorg. Chem., 2007, 46, 8496–8498. 18 S. Reinartz, P. S. White, M. Brookhart and J. L. Templeton, J. Am. Chem. Soc., 2001, 123, 6425–6426. 19 P. Sangtrirutnugul and T. D. Tilley, Organometallics, 2008, 27, 2223– 2230. 20 N. M. West, P. S. White, J. L. Templeton and J. F. Nixon, Organometallics, 2009, 28, 1425–1434. 21 S. B. Zhao, G.Wu and S.Wang, Organometallics, 2008, 27, 1030–1033. 22 J. L. McBee and T. D. Tilley, Organometallics, 2009, 28, 3947–3952. 23 S. H. Crosby, G. J. Clarkson, R. J. Deeth and J. P. Rourke, Organometallics, 2010, 29, 1966–1976. 24 A. Baber, C. Fan, D.W. Norman, A. G. Orpen, P. G. Pringle and R. L. Wingad, Organometallics, 2008, 27, 5906–5910. 25 W. H. Bernskoetter, C. K. Schauer, K. I. Goldberg and M. Brookhart, Science, 2009, 326, 553–556. 26 A. B. Chaplin and A. S. Weller, Organometallics, 2010, 29, 2332–2342. 27 B. L. Conley and T. J. Williams, J. Am. Chem. Soc., 2010, 132, 1764– 1765.
URI: http://wrap.warwick.ac.uk/id/eprint/40579

Request changes to a record

Actions (login required)

View Item View Item