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Platinum(iv) centres with agostic interactions from either sp2 or sp3 C–H bonds
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Crosby, Sarah H., Deeth, Robert J., Clarkson, Guy J. and Rourke, Jonathan (2011) Platinum(iv) centres with agostic interactions from either sp2 or sp3 C–H bonds. Dalton Transactions, Vol.40 (No.6). pp. 1227-1229. doi:10.1039/c0dt01428a
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Official URL: http://dx.doi.org/10.1039/c0dt01428a
Abstract
Agostic complexes of platinum(IV) have been isolated and characterised. A Pt(II) sp(3) agostic complex maintains the agostic interaction upon oxidation giving a Pt(IV) sp(3) agostic complex; in another Pt(IV) complex the agostic interaction from an sp(2) C-H bond is sufficient to displace another ligand.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Platinum, Organometallic chemistry, Complex compounds -- Synthesis, Platinum -- Oxidation, Chemical bonds | ||||
| Journal or Publication Title: | Dalton Transactions | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1477-9226 | ||||
| Official Date: | 2011 | ||||
| Dates: |
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| Volume: | Vol.40 | ||||
| Number: | No.6 | ||||
| Page Range: | pp. 1227-1229 | ||||
| DOI: | 10.1039/c0dt01428a | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Funder: | University of Warwick, Advantage West Midlands (AWM), European Regional Development Fund (ERDF) |
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