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Platinum(iv) centres with agostic interactions from either sp2 or sp3 C–H bonds

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Crosby, Sarah H., Deeth, Robert J., Clarkson, Guy J. and Rourke, Jonathan P.. (2011) Platinum(iv) centres with agostic interactions from either sp2 or sp3 C–H bonds. Dalton Transactions, Vol.40 (No.6). pp. 1227-1229. ISSN 1477-9226

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Abstract

Agostic complexes of platinum(IV) have been isolated and characterised. A Pt(II) sp(3) agostic complex maintains the agostic interaction upon oxidation giving a Pt(IV) sp(3) agostic complex; in another Pt(IV) complex the agostic interaction from an sp(2) C-H bond is sufficient to displace another ligand.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Platinum, Organometallic chemistry, Complex compounds -- Synthesis, Platinum -- Oxidation, Chemical bonds
Journal or Publication Title: Dalton Transactions
Publisher: Royal Society of Chemistry
ISSN: 1477-9226
Official Date: 2011
Volume: Vol.40
Number: No.6
Page Range: pp. 1227-1229
Identification Number: 10.1039/c0dt01428a
Status: Peer Reviewed
Publication Status: Published
Funder: University of Warwick, Advantage West Midlands (AWM), European Regional Development Fund (ERDF)
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URI: http://wrap.warwick.ac.uk/id/eprint/40579

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