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Synthesis of functional polymers by post-polymerization modification

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Gauthier, Marc A., Gibson, Matthew I. and Klok, Harm-Anton (2008) Synthesis of functional polymers by post-polymerization modification. Angewandte Chemie International Edition, Vol.48 (No.1). pp. 48-58. doi:10.1002/anie.200801951

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Official URL: http://dx.doi.org/10.1002/anie.200801951

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Abstract

Post-polymerization modification is based on the direct polymerization or copolymerization of monomers bearing chemoselective handles that are inert towards the polymerization conditions but can be quantitatively converted in a subsequent step into a broad range of other functional groups. The success of this method is based on the excellent conversions achievable under mild conditions, the excellent functional-group tolerance, and the orthogonality of the post-polymerization modification reactions. This Review surveys different classes of reactive polymer precursors bearing chemoselective handles and discusses issues related to the preparation of these reactive polymers by direct polymerization of appropriately functionalized monomers as well as the post-polymerization modification of these precursors into functional polymers.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH): Polymerization, Copolymers, Monomers
Journal or Publication Title: Angewandte Chemie International Edition
Publisher: Wiley - V C H Verlag GmbH & Co. KGaA
ISSN: 1433-7851
Official Date: 22 December 2008
Dates:
DateEvent
22 December 2008Published
Volume: Vol.48
Number: No.1
Page Range: pp. 48-58
DOI: 10.1002/anie.200801951
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Fonds québécois de la recherche sur la nature et les technologies (FCAR), European Union (EU)
Grant number: NMP4-CT-2006-026723 (EU)

Data sourced from Thomson Reuters' Web of Knowledge

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