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Synthesis of functional polymers by post-polymerization modification
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Gauthier, Marc A., Gibson, Matthew I. and Klok, Harm-Anton (2008) Synthesis of functional polymers by post-polymerization modification. Angewandte Chemie International Edition, Vol.48 (No.1). pp. 48-58. doi:10.1002/anie.200801951
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Official URL: http://dx.doi.org/10.1002/anie.200801951
Abstract
Post-polymerization modification is based on the direct polymerization or copolymerization of monomers bearing chemoselective handles that are inert towards the polymerization conditions but can be quantitatively converted in a subsequent step into a broad range of other functional groups. The success of this method is based on the excellent conversions achievable under mild conditions, the excellent functional-group tolerance, and the orthogonality of the post-polymerization modification reactions. This Review surveys different classes of reactive polymer precursors bearing chemoselective handles and discusses issues related to the preparation of these reactive polymers by direct polymerization of appropriately functionalized monomers as well as the post-polymerization modification of these precursors into functional polymers.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science > Chemistry | ||||
| Library of Congress Subject Headings (LCSH): | Polymerization, Copolymers, Monomers | ||||
| Journal or Publication Title: | Angewandte Chemie International Edition | ||||
| Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
| ISSN: | 1433-7851 | ||||
| Official Date: | 22 December 2008 | ||||
| Dates: |
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| Volume: | Vol.48 | ||||
| Number: | No.1 | ||||
| Page Range: | pp. 48-58 | ||||
| DOI: | 10.1002/anie.200801951 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Funder: | Fonds québécois de la recherche sur la nature et les technologies (FCAR), European Union (EU) | ||||
| Grant number: | NMP4-CT-2006-026723 (EU) |
Data sourced from Thomson Reuters' Web of Knowledge
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