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Organogelation of sheet–helix diblock copolypeptides

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Gibson, Matthew I. and Cameron, Neil R. (2008) Organogelation of sheet–helix diblock copolypeptides. Angewandte Chemie International Edition, Vol.47 (No.28). pp. 5160-5162. doi:10.1002/anie.200801056

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Official URL: http://dx.doi.org/10.1002/anie.200801056

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Abstract

Together they're strong: Block copolypeptides containing poly(benzyl-l-threonine) and an α-helical block are effective organogelators despite the high solubility of the constituent homopolymers. An unexpected conformational change in the first block, from random coil to β sheet, directs the assembly into stacked lamellae (see picture).

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science > Chemistry
Faculty of Science > Engineering
Library of Congress Subject Headings (LCSH): Gelation, Colloids, Peptides, Self-assembly (Chemistry), Polymerization
Journal or Publication Title: Angewandte Chemie International Edition
Publisher: Wiley - V C H Verlag GmbH & Co. KGaA
ISSN: 1433-7851
Official Date: 27 June 2008
Dates:
DateEvent
27 June 2008Published
Volume: Vol.47
Number: No.28
Page Range: pp. 5160-5162
DOI: 10.1002/anie.200801056
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access

Data sourced from Thomson Reuters' Web of Knowledge

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