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Organogelation of sheet–helix diblock copolypeptides
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Gibson, Matthew I. and Cameron, Neil R. (2008) Organogelation of sheet–helix diblock copolypeptides. Angewandte Chemie International Edition, Vol.47 (No.28). pp. 5160-5162. doi:10.1002/anie.200801056 ISSN 1433-7851.
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Official URL: http://dx.doi.org/10.1002/anie.200801056
Abstract
Together they're strong: Block copolypeptides containing poly(benzyl-l-threonine) and an α-helical block are effective organogelators despite the high solubility of the constituent homopolymers. An unexpected conformational change in the first block, from random coil to β sheet, directs the assembly into stacked lamellae (see picture).
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry Faculty of Science, Engineering and Medicine > Engineering > Engineering |
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| Library of Congress Subject Headings (LCSH): | Gelation, Colloids, Peptides, Self-assembly (Chemistry), Polymerization | ||||
| Journal or Publication Title: | Angewandte Chemie International Edition | ||||
| Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
| ISSN: | 1433-7851 | ||||
| Official Date: | 27 June 2008 | ||||
| Dates: |
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| Volume: | Vol.47 | ||||
| Number: | No.28 | ||||
| Page Range: | pp. 5160-5162 | ||||
| DOI: | 10.1002/anie.200801056 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
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