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Solid-state NMR characterisation of the thermal transformation of a Hungarian white illite

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Carroll, Donna L., Kemp, Thomas F., Bastow, T. J. and Smith, Mark E.. (2005) Solid-state NMR characterisation of the thermal transformation of a Hungarian white illite. Solid State Nuclear Magnetic Resonance, Vol. 2 (No. 1). pp. 31-43. ISSN 0926-2040

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Official URL: http://dx.doi.org/10.1016/j.ssnmr.2005.04.001

Abstract

1H, 27Al, 29Si and 39K solid-state NMR are reported from a Hungarian illite 2:1 clay for samples heated up 1600 °C. This single-phase sample has a small amount of aluminium substitution in the silica layer and very low iron-content (0.4 wt%). Thermal analysis shows several events that can be related to features in the NMR spectra, and hence changes in the atomic scale structure. As dehydroxylation occurs there is increasing AlO4 and AlO5-contents. The silica and gibbsite layers become increasingly separated as the dehydroxylation progresses. Between 900 and 1000 °C the silica layer forms a potassium aluminosilicate glass. The gibbsite-layer forms spinel/γ-Al2O3 and some aluminium-rich mullite. Then on heating to 1600 °C changes in the 29Si and 27Al MAS NMR spectra are consistent with the aluminosilicate glass increasing its aluminium-content, the amount of mullite increasing probably with its silicon-content also increasing, and some α-Al2O3 forming.

Item Type:

Journal Article

Subjects:

Q Science > QC Physics

Divisions:

Administration > Vice Chancellor's Office
Faculty of Science > Physics

Library of Congress Subject Headings (LCSH):

Illite, Solid state physics, Clay minerals

Journal or Publication Title:

Solid State Nuclear Magnetic Resonance

Publisher:

Academic Press

ISSN:

0926-2040

Official Date:

July 2005

Dates:

Date	Event
July 2005	Published

Volume:

Vol. 2

Number:

No. 1

Page Range:

pp. 31-43

Identification Number:

10.1016/j.ssnmr.2005.04.001

Status:

Peer Reviewed

Access rights to Published version:

Restricted or Subscription Access

Funder:

Leverhulme Trust (LT), Engineering and Physical Sciences Research Council (EPSRC), University of Warwick, Nuffield Foundation (NF), Riga Technical University

References:

[1] G.W. Brindley, M. Nakahira, J. Am. Ceram. Soc. 42 (1959) 311.
[2] G.W. Brindley, J. Lemaitre, Chemistry of Clays and Clay Minerals, Longman, Harlow, 1990.
[3] W.E. Worrall, Clays and Ceramic Raw Materials, Elsevier Applied Science, Barking, 1986.
[4] R. E. Grim, R. H. Bray, W. F. Bradley, Am. Mineral. 22 (1937) 813.
[5] W.A. Deer, R.A. Howie, J. Zussman, An Introduction to the Rock-Forming Minerals. Longman Group, Hong Kong 1992.
[6] C.M. Earnest, Lecture Notes in Earth Sciences, Springer-Verlag Berlin, (1991) 270.
[7] R.E. Grim, W.F. Bradley, J. Am. Ceram. Soc. 22 (1940) 242.
[8] P.J. Michael, W.R. McWhinnie Polyhedron 8 (1989) 2709.
[9] E. Murad, U. Wagner, Clay Minerals 31 (1996) 45.
[10] G. Engelhardt, D. Michel, High Resolution Solid-State NMR of Silicates and Zeolites. John Wiley and Sons. Chichester (1987).
[11] K.J.D. MacKenzie, M.E. Smith, Multinuclear Solid State NMR of Inorganic Materials, Pergamon, Oxford, (2002).
[12] M.E. Smith, Appl. Magn. Reson. 4 (1993) 1.
[13] D.E. Woessner, Am. Mineral. 74 (1989) 203.
[14] K.J.D. Mackenzie, I.W.M. Brown, R.H. Meinhold, M.E. Bowden, J. Am. Ceram. Soc. 68 (1985) 293.
[15] T. Watanabe, H. Shimizu, K. Nagasawa, A. Masuda, H. Saito, Clay Minerals 22 (1987) 37.
[16] J. Sanz, A. Madani, J.M. Serratosa, J.S. Moya, S. Aza, J. Am. Ceram. Soc. 71 (1988) C418.
[17] J.F. Lambert, W.S. Millman, J.J. Fripiat, J. Am. Chem. Soc. 111 (1989) 3517.
[18] J. Rocha, J. Klinowski, Phys. Chem. Minerals 17 (1990) 179.
[19] R.C.T. Slade, T.W. Davis, J. Mater. Chem. 1 (1991) 361.
[20] D. Massiot, P. Dion, J. Alcover, F. Bergaya, J. Am. Ceram. Soc. 78 (1995) 2940.
[21] K.J.D. Mackenzie, J.S. Hartman, K. Okada, J. Am. Ceram. Soc. 79 (1996) 2980.
[22] P.A. Schroeder, R.J. Pruett, Am. Mineral. 81 (1996) 26.
[23] J. Rocha, J. Phys. Chem. B 103 (1999) 9801.
[24] H.P. He, J.G. Guo, J.X. Zhu, C. Hu, Clay Minerals 38 (2003) 551.
[25] M.E. Smith, G.S. Neal, M.B. Trigg, J. Drennan, Appl. Magn. Reson. 4, (1993) 157.
[26] J.J. Fitzgerald, S.F. Dec, A.I. Hamza, Am. Mineral. 74 (1989) 1405.
[27] P.J. Sanchez-Soto, I. Sobrados, J. Sanz, J.L. Rodriguez, J. Am. Ceram. Soc. 76 (1993) 3024.
[28] J.J. Fitzgerald, A.I. Hamza, S.F. Dec, C.E. Bronnimann, J. Phys. Chem. 100 (1996) 17351.
[29] I.W.M. Brown, K.J.D. MacKenzie, R.H. Meinhold, J. Mater. Sci. 22 (1987) 3265.
[30] S.R. Drachman, G.E. Roch, M.E. Smith, Solid State NMR 9 (1997) 257.
[31] G.E. Roch, M.E. Smith, S.R. Drachman, Clays and Clay Minerals 46 (1998) 694.
[32] C.J. McConville, G.E. Roch, W.E. Lee, M.E. Smith, CIMTEC 2002 “Science for New Technology of Silicate Ceramics” (2003) 97.
[33] M.E. Smith, Ann. Rep. NMR Spectro. 43 (2000) 121.
[34] T.J. Bastow, J. Chem. Soc., Faraday Trans. 87 (1991) 2453.
[35] J.-F. Lambert, R. Prost, M.E. Smith, Clays and Clay Minerals 40 (1992) 253.
[36] A.C. Kunwar, G.L. Turner, E. Oldfield, J. Magn. Reson. 69 (1986) 124.
[37] M.E. Smith, E.R.H. van Eck, Prog. NMR Spectrosc. 34 (1999) 159.
[38] T.F. Kemp, MSc Thesis, University of Warwick (2004).
[39] D. Massiot, C. Bessada, J.P. Coutures, F. Taulelle, J. Magn. Reson. 90 (1990) 231.
[40] S. Hayashi, T. Ueda, K. Hamamizu, E. Akiba, J. Phys. Chem. 96 (1992) 10922.
[41] J. Sanz, J.M. Serratosa, J. Am. Chem. Soc. 106 (1984) 4790.
[42] C.P. Herrero, J. Sanz, J.M. Serratosa, J. Phys. Chem. 93 (1989) 4311.
[43] S.K. Lausen, H.Lindgreen, H.J. Jakobsen, N.C. Nielsen, Am. Mineral. 84 (1999) 1433
[44] V.A. Drits, G. Besson, F. Muller, Clays and Clay Minerals 43 (1995) 718.
[45] D. Freude, Encyclopedia of Analytical Chemistry, Ed. R.A. Meyer, John Wiley and Sons Ltd, Chichester, (2000) 12188.
[46] G. Kunath-Fandrei, T.J. Bastow, J.S. Hall, C. Jäger, M.E. Smith, J. Phys. Chem. 99 (1995) 15138.
[47] J.F. Schairer, N.L. Bowen, Bull. Soc. Geol. Finlande 20 (1947) 74
[48] J.S. Brown, in Phase Diagrams in Advanced Ceramics, Ed. A.M. Alper, p55 Academci Press, London, 1995.
[49] L.H. Merwin, A. Sebald, H. Rager, H. Schneider, Phys. Chem. Minerals 18 (1991) 47.
[50] G. Kunath-Fandrei, P. Rehak, S. Steuernagel, C. Jäger, Solid State NMR 3 (1994) 241.[51] I. Jaymes, A. Douy, D. Massiot, J.P. Coutures, J. Chim. Phys. PCB 92 (1995) 1851
[52] P. Rehak, G. Kunath-Fandrei, P. Losso, B. Hildmann, H. Schneider, C. Jäger, Am. Mineral. 83 (1998) 1266.
[53] T. Ban, K. Okada, J. Am. Ceram. Soc. 76 (1993) 2491.
[54] I. Jaymes, A. Douy, D. Massiot, J.P. Coutures, J. Non-Cryst. Solids 204 (1996) 125.